Journal ArticleDOI
Novel Adsorption and Desorption Chemiluminescence of 10,10′-Disubstituted 9,9′(10H,10′H)-Biacridinylidenes in Alumina Slurries
Sachiko Yamada,Koko Maeda +1 more
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TLDR
In this article, the effects of solvent polarity and alumina activity on the generation of chemiluminescence (CL) in an alumina slurry were investigated and the mechanism was clarified.Abstract:
10,10′-Disubstituted 9,9′(10H,10′H)-biacridinylidene (1) has a novel chemiluminescence (CL) in an alumina slurry. The CL is yellowish green emissions I and II from the excited singlet state of adsorbed 1 onto alumina, 11*(ads), and blue emission III from the excited singlet state of 10-substituted 9(10H)-acridinone (2), 12*. In this study the effects of alumina activity and solvent polarity on the generation of those emitters were investigated and the mechanism was clarified: 1) 11*(ads) is generated by two-step electron transfers, the first electron transfer from 1 to O2 gives 1+•(ads) accompanied by adsorption of 1 and the following electron transfer from –OH and/or –O− on alumina to 1+•(ads) gives 11*(ads), and 2) 12* is generated from the reaction of 12+ and O2−•, both of which are formed during the reaction of emissions I and II. The two key compounds, 12+ and O2−•, were detected spectroscopically. O2−• in a slurry of 1, benzene, and highly activated alumina was found to be extremely stable and to ge...read more
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Journal ArticleDOI
Substituent effects on the kinetics for the chemiluminescence reaction of 6-arylimidazo[1,2-a]pyrazin-3(7H)-ones (Cypridina luciferin analogues) : support for the single electron transfer (SET)-oxygenation mechanism with triplet molecular oxygen
TL;DR: Kinetics of chemiluminescence reactions of 2-methyl-6-phenylimidazo[1,2-a]pyrazin-3(7H)-one (1c) and substituent effects of the 6-aryl group of derivatives 1 strongly suggest that the rate-determining step is a single electron transfer from an anion derived from 1 to a triplet molecular oxygen (O2) in the oxygenation process.
Patent
Derivatives of acridinone as anti-parasitic, anti-fungal and anti-viral agents
Rolando F. Pellon Condom,Maite L. Docampo Palacios,Gilberto L. Pardo Andreu,Aymé Fernández-Calienes Valdés,Bárbara Judith Mendiola Martínez,Lázara Rojas Rivero,Norma Beatriz D'accorso Haicck,Mirta Liliana Fascio Silva,Elsa Beatriz Damonte Lotito,Cybele Carina García Cattebeke,Claudia Soledad Sepúlveda Suchecki,Maria Belén Mazzucco Gavieiro,Laura Beatriz Talarico Salinas,Louis Maes +13 more
TL;DR: In this paper, the synthesis and evaluation of novel organic products as anti-parasitic, anti-fungal and anti-viral agents were discussed. And the authors proposed a family of acridinones, 10-{[3-(6-hydroxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-il)-4,5-dihydro-5 -isoxazolyl] methyl}-9(10H) acrid
Patent
Derivados de la acridinona como agentes antiparasitarios, antifungicos y antivirales.
Condom Rolando F. Pellon,Palacios Maite L. Docampo,Andreu Gilberto L. Pardo,Calienes Valdés Aymé Fernández,Martínez Bárbara Judith Mendiola,Rivero Lázara Rojas,Haicck Norma Beatriz D'accorso,Silva Mirta Liliana Fascio,Lotito Elsa Beatriz Damonte,Cattebeke Cybele Carina García,Suchecki Claudia Soledad Sepúlveda,Gavieiro Maria Belén Mazzucco,Salinas Laura Beatriz Talarico,Louis Maes +13 more
TL;DR: In this article, nuevos derivados of the 10-alil- (I), 10-(3metil-2-butenil)- (II) and 10-(1,2propanodienil)-9(10H)-acridinona (III) and nueva familia de acridinonas, the 10 -{[3]-[6-hidroxi-2,2-dimetiltetrahidrofuro[2,3-d][1,3]dioxol-5
Journal ArticleDOI
Novel Adsorption and Desorption Chemiluminescence of 10,10′- Disubstituted 9,9′(10H,10′H)-Biacridinylidenes in Alumina Slurries.
Sachiko Yamada,Koko Maeda +1 more
TL;DR: In this paper, the effects of solvent polarity and alumina activity on the generation of chemiluminescence (CL) in an alumina slurry were investigated and the mechanism was clarified.
References
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Acid-base properties and catalytic activity of solid surfaces
Ken-ichi Tanaka,Atsumu Ozaki +1 more
TL;DR: In this paper, a generalized electronegativity of the metal ion (Xi) was found to increase the acidity and catalytic activity of the catalysts, which is explained by the inductive effect of metal ions in the catalyst.
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Electrochemically generated chemiluminescence of lucigenin
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Test of the nonane method for micropore evaluation. Use of nitrogen, n-hexane and carbon tetrachloride as adsorptives with ammonium phosphomolybdate, phosphotungstate and silicomolybdate as absorbents
S. John Gregg,M. Mohammad Tayyab +1 more
TL;DR: In this article, the adsorption isotherms of nitrogen, n-hexane and carbon tetrachloride on each of three microporous solids have been determined gravimetrically both before and after pre-adsorption of n-nonane.
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Ionic limiting partial molal volumes in various solvents
TL;DR: In this article, a comparative study of the text-decoration:overline-V0R4N+ values obtained by Conway, Verrall and Desnoyers for the calculation of ionic partial molal volumes at infinite dilution in various solvents was performed.
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