Journal ArticleDOI
Novel Cobalt‐ and Nickel‐Clusters with S and PPh3 as Ligands; Crystal Structures of [Co7S6(PPh3)5Cl2], [Co6S8(PPh3)6]+[CoCl3(THF)]−, [Ni8S6Cl2(PPh3)6], and [Ni8S5(PPh3)7]
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This article is published in Angewandte Chemie.The article was published on 1985-08-01. It has received 71 citations till now. The article focuses on the topics: Cobalt & Nickel.read more
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New Co and Ni Clusters with Se and PPh3 as Ligands: [Co4(μ3‐Se)4(PPh3)4], [Co6(μ3‐Se)8(PPh3)6], [Co9(μ4‐Se)3(μ3‐Se)8(PPh3)6], and [Ni34(μ5‐Se)2(μ4‐Se)20(PPh3)10]
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Hydrido copper clusters supported by dithiocarbamates: oxidative hydride removal and neutron diffraction analysis of [Cu7(H){S2C(aza-15-crown-5)}6].
Ping-Kuei Liao,Ching-Shiang Fang,Alison J. Edwards,Samia Kahlal,Samia Kahlal,Jean-Yves Saillard,Jean-Yves Saillard,C. W. Liu +7 more
TL;DR: This is the first time that hydride encapsulated within a copper cluster can be released as H(2) via chemical means, and all complexes have been fully characterized by (1)H NMR, FT-IR, UV-vis, and elemental analysis.
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Neue Übergangsmetallcluster‐Komplexe mit Liganden der fünften und sechsten Hauptgruppe
TL;DR: In this article, a vielseitig anwendbares und ausbaufahiges Verfahren zur Synthese von Metallclustern beschrieben.
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Review of the synthesis and properties of colloidal quantum dots: the evolving role of coordinating surface ligands
Christopher M. Evans,Laura C. Cass,Kathryn E. Knowles,Daniel B. Tice,Robert P. H. Chang,Emily A. Weiss +5 more
TL;DR: In this paper, a review highlights the developments in synthetic methods for colloidal quantum dots that have expanded the range of achievable sizes, shapes, materials, and surface chemistries over the past 30 years and how these methods have enabled optimization of properties like photoluminescence quantum yield, monodisperse size distributions, and conductivity in the solid state.
References
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A Molecular Orbital Treatment of the Bonding in Certain Metal Atom Clusters
F. A. Cotton,Terry E. Haas +1 more
TL;DR: In this article, the metal-metal bonding within the clusters is treated by a simple molecular orbital method, and it is shown that in this way all the general aspects of the electronic structures can be straightforwardly accounted for.
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The bonding capabilities of transition metal clusters
TL;DR: In this article, a new classification scheme for transition metal carbonyl cluster compounds is proposed, which is defined as those which use all available Cluster Valence Molecular Orbitals, CVMOs, Class II cluster compounds have s and p CVMO's vacant and Class III clusters have vacant dCVMOs.
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Sulfur Atoms as Ligands in Metal Complexes
TL;DR: The types of sulfur bonding that occur in the molecules of maingroup elements are almost unknown in the chemistry of metal complexes, where the sulfur atoms function instead as two-electron donors as discussed by the authors.
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Schwefelatome als Liganden in Metall‐Komplexen
TL;DR: Aus der Hauptgruppen-Molekulchemie gelaufigen Bindungsarten des Schwefels als Sulfan oder Sulfid sind in der Metallkomplex-Chemie fast unbekannt as mentioned in this paper.