Journal ArticleDOI
New Co and Ni Clusters with Se and PPh3 as Ligands: [Co4(μ3‐Se)4(PPh3)4], [Co6(μ3‐Se)8(PPh3)6], [Co9(μ4‐Se)3(μ3‐Se)8(PPh3)6], and [Ni34(μ5‐Se)2(μ4‐Se)20(PPh3)10]
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This article is published in Angewandte Chemie.The article was published on 1985-11-01. It has received 112 citations till now.read more
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A 3D Coordination Framework Based on Linkages of Nanosized Hydroxo Lanthanide Clusters and Copper Centers by Isonicotinate Ligands
Journal ArticleDOI
Synthesis and crystal structures of the ligand-stabilized silver chalcogenide clusters [Ag154Se77(dppxy)18], [Ag320(StBu)60S130(dppp)12], [Ag352S128(StC5H11)96], and [Ag490S188(StC5H11)114].
Christopher E. Anson,Andreas Eichhöfer,Ibrahim Issac,Dieter Fenske,Olaf Fuhr,Paloma Sevillano,Claudia Persau,Dietmar Stalke,Jiatao Zhang +8 more
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Unique nanoscale {CuII36LnIII24} (Ln = Dy and Gd) metallo-rings
TL;DR: Two unprecedented 3d-4f hexagonal metallo-rings with a diagonal dimension of about 4.6 nm were facilely synthesized by self-assembly of Cu(II), Ln(III) nitrates and benzoate in the presence of triethylamine.
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Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions
Constantina Papatriantafyllopoulou,Eleni E. Moushi,George Christou,Anastasios J. Tasiopoulos +3 more
TL;DR: The research field of giant clusters is under continuous evolution and their intriguing structural characteristics and magnetism properties that attract the interest of synthetic Inorganic Chemists promise a brilliant future for this class of compounds.
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Multiple Bonds between Transition Metals and “Bare” Main Group Elements: Links between Inorganic Solid State Chemistry and Organometallic Chemistry
TL;DR: In this article, a review of metal-metal multiple-bond structures with substituent-free (bare) main group elements can be found in the context of preconditioned organometallic chemistry.
References
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A Molecular Orbital Treatment of the Bonding in Certain Metal Atom Clusters
F. A. Cotton,Terry E. Haas +1 more
TL;DR: In this article, the metal-metal bonding within the clusters is treated by a simple molecular orbital method, and it is shown that in this way all the general aspects of the electronic structures can be straightforwardly accounted for.
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The bonding capabilities of transition metal clusters
TL;DR: In this article, a new classification scheme for transition metal carbonyl cluster compounds is proposed, which is defined as those which use all available Cluster Valence Molecular Orbitals, CVMOs, Class II cluster compounds have s and p CVMO's vacant and Class III clusters have vacant dCVMOs.
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Un nouveau sulfure de molybdene : Mo3S4 preparation, proprietes et structure cristalline
TL;DR: In this paper, a nouveau sulfure de molybdene : Mo3S4, isostructural de Mo3Se4, a ete prepare.
Journal ArticleDOI
Applications of topological electron-counting theory to polyhedral metal clusters
TL;DR: Application of the theory de comptage des electrons, developpee ibid, 1251-1257, a un grand nombre d'agregats polynucleaires de complexes de metaux de transition principalement, constitue une alternative a la theorie des paires electroniques du squelette for relier entre elles les structures polyedriques connues and en prevoir de nouvelles as mentioned in this paper.