Reference EntryDOI
Novel Electrochemical Techniques in Corrosion Research
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TLDR
In this paper, an experimental investigation of Corrosion Reactions by analysis of the Corrosions Products was conducted by following the Chemical Reaction Rate (CRR) following the rate of the Electrochemical CORrosion Reaction (ECR).Abstract:
The sections in this article are
Introduction
Experimental Investigation of Corrosion Reactions by Analysis of the Corrosion Products
Experimental Investigation of Corrosion Reactions by Following the Chemical Reaction Rate
Experimental Investigation of Corrosion Reactions by Following the Rate of the Electrochemical Corrosion Reaction
Electrochemical Impedance Spectroscopy and Noise Analysis
Introduction
The Principle of Dynamic System Analysis
Measurement of the Electrochemical Impedance
Presentation of Impedance Data
Interpretation of Impedance Data
The Polarization Resistance
Frequency Dispersion
Surface Inhomogeneities
Single Layer Impedance Model
Sandwich Layer Impedance Model
Equivalent Circuit Versus Transfer Function
The Transport Impedance
Iron Corrosion in Neutral Solution
Impedance Model of Passive Films
Metal Dissolution and Active-to-Passive Transition
Electrochemical Noise
Noise Sources in Electrochemical Systems
Noise Measurement Techniques
Data Processing
Noise Resistance and Polarization Resistance
The Scanning Vibrating Electrode Technique
Introduction
History of Scanning Reference Electrodes
Basic Principles of Localized Potential Mapping
Localized Electrochemical Impedance Spectroscopy (LEIS)
Applications of Modern Scanning Electrode Techniques
Local Breakdown of Passivity
Galvanic Corrosion
Inhibition
Microbiologically Influenced Corrosion
Protective Polymeric Coatings
Concluding Remarks
Scanning Kelvinprobe
Introduction
Theory of the Vibrating Condenser Method
The Relation between the Volta Potential Difference and Corrosion-Relevant Properties
Electrolyte Covered Metal Surfaces
Metals in Humid Air
Polymer-Coated Metals
Calibration of the Kelvinprobe
Application of the Kelvinprobe: Atmospheric Corrosion
Experimental
Results
Application of the Kelvinprobe: Corrosion Protection by Organic Coatings
Experimental
Polymer-Coated Steel
Polymer Coated Galvanized Steel
Polymer Coated Aluminum Alloys
Industrial Coatings
Application of the Kelvinprobe: Corrosion Protection by Modified Metal Surfaces
Metal Surfaces Modified by Monolayers of Organic Molecules
Metal Surfaces Modified by Ultra-Thin Plasma Polymers
Metal Surfaces Modified by Inorganic and Organic Layersread more
Citations
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ADHESION AND DE-ADHESION MECHANISMS AT POLYMER/METAL INTERFACES: Mechanistic Understanding Based on In Situ Studies of Buried Interfaces
TL;DR: In this article, the authors highlight the state-of-the-art research regarding the application of modern in situ spectroscopic, microscopic, and electrochemical techniques to improve the understanding of the interaction of organic molecules with metal surfaces.
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Review—On the Application of the Scanning Vibrating Electrode Technique (SVET) to Corrosion Research
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Corrosion inhibition of pure Mg containing a high level of iron impurity in pH neutral NaCl solution
Junjie Yang,Carsten Blawert,Sviatlana V. Lamaka,Kiryl A. Yasakau,Li Wang,Daniel Laipple,Mauricio Schieda,Shichun Di,Mikhail L. Zheludkevich +8 more
TL;DR: In this paper, three sodium salts of organic acids (2,5-pyridinedicarboxylic, 3-methylsalicylic and fumaric) were studied as corrosion inhibitors for pure magnesium containing a high level of Fe impurity.
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Corrosion protection of Zn-phosphate containing water borne dispersion coatings: Part 2: Investigations of the corrosive de-adhesion of model latex coatings on iron
TL;DR: In this paper, unmodified and chemically modified Zn-phosphate pigments were investigated with regard to corrosion inhibiting properties in combination with the model latex films and the nature of these pigments and their location in the coating influencing the de-adhesion kinetics in corrosive environments.
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Corrosion stability of polymer-coated metals-new concepts based on fundamental understanding
TL;DR: In this paper, the corrosion and de-adhesion of polymers from reactive metal surfaces is described. But the authors do not consider the effect of the electronic structure of polymeric coatings.
References
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TL;DR: In this paper, the locus of the dielectric constant in the complex plane was defined to be a circular arc with end points on the axis of reals and center below this axis.
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The Point Defect Model for the Passive State
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Electrochemical impedance spectroscopy (EIS) of corrosion processes on inhomogeneous surfaces
TL;DR: In this article, the influence of surface inhomogeneities on corrosion processes is demonstrated by electrochemical impedance spectroscopy (EIS), and experimental impedance data obtained in different systems are discussed on the basis of transfer function analysis.