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Journal ArticleDOI

On the Dirac Theory of Spin 1/2 Particles and Its Non-Relativistic Limit

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TLDR
In this paper, a canonical transformation on the Dirac Hamiltonian for a free particle is obtained in which positive and negative energy states are separately represented by two-component wave functions.
Abstract
By a canonical transformation on the Dirac Hamiltonian for a free particle, a representation of the Dirac theory is obtained in which positive and negative energy states are separately represented by two-component wave functions. Playing an important role in the new representation are new operators for position and spin of the particle which are physically distinct from these operators in the conventional representation. The components of the time derivative of the new position operator all commute and have for eigenvalues all values between $\ensuremath{-}c$ and $c$. The new spin operator is a constant of the motion unlike the spin operator in the conventional representation. By a comparison of the new Hamiltonian with the non-relativistic Pauli-Hamiltonian for particles of spin \textonehalf{}, one finds that it is these new operators rather than the conventional ones which pass over into the position and spin operators in the Pauli theory in the non-relativistic limit. The transformation of the new representation is also made in the case of interaction of the particle with an external electromagnetic field. In this way the proper non-relativistic Hamiltonian (essentially the Pauli-Hamiltonian) is obtained in the non-relativistic limit. The same methods may be applied to a Dirac particle interacting with any type of external field (various meson fields, for example) and this allows one to find the proper non-relativistic Hamiltonian in each such case. Some light is cast on the question of why a Dirac electron shows some properties characteristic of a particle of finite extension by an examination of the relationship between the new and the conventional position operators.

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Journal ArticleDOI

Selected topics in the large quantum number expansion

TL;DR: In this article, the authors study quantum field theories and conformal field theories with global symmetries in the limit of large charge for some of the generators of the symmetry group.
Journal ArticleDOI

Linear response formalism for the Douglas–Kroll–Hess approach to the Dirac–Kohn–Sham problem: First‐ and second‐order nuclear displacement derivatives of the energy

TL;DR: An implementation of analytic force constants in a quasi-relativistic (scalar) model constructed by the commonly used DKH transformation of second order in the nuclear potential only is presented.
Journal ArticleDOI

Semiclassical dynamics and nonlinear charge current

TL;DR: In this article, the authors review the general semiclassical framework of the nonlinear charge currents and propose a universal treatment of electron dynamics up to second order expressed in the basis of the unperturbed states.
Journal ArticleDOI

Spherical delta functions and multipole expansions

TL;DR: In this article, the Cartesian Taylor series for an analytic function in three dimensions is rewritten as a series of solid spherical harmonics, and a discussion of the distribution theory definition of singular spherical harmonic functions is given, which leads to a definition of spherical delta functions.
Book ChapterDOI

Relativistic Many-Body Perturbation Theory

TL;DR: The effects of special relativity on the energy levels of one-electron atoms are well known as mentioned in this paper, and the relativistic theory of quantum electrodynamics (QED) has led to the development of one of the most powerful and elegant branches of modern physics, where experiment and theory are in excellent agreement.
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