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Journal ArticleDOI

On the Dirac Theory of Spin 1/2 Particles and Its Non-Relativistic Limit

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TLDR
In this paper, a canonical transformation on the Dirac Hamiltonian for a free particle is obtained in which positive and negative energy states are separately represented by two-component wave functions.
Abstract
By a canonical transformation on the Dirac Hamiltonian for a free particle, a representation of the Dirac theory is obtained in which positive and negative energy states are separately represented by two-component wave functions. Playing an important role in the new representation are new operators for position and spin of the particle which are physically distinct from these operators in the conventional representation. The components of the time derivative of the new position operator all commute and have for eigenvalues all values between $\ensuremath{-}c$ and $c$. The new spin operator is a constant of the motion unlike the spin operator in the conventional representation. By a comparison of the new Hamiltonian with the non-relativistic Pauli-Hamiltonian for particles of spin \textonehalf{}, one finds that it is these new operators rather than the conventional ones which pass over into the position and spin operators in the Pauli theory in the non-relativistic limit. The transformation of the new representation is also made in the case of interaction of the particle with an external electromagnetic field. In this way the proper non-relativistic Hamiltonian (essentially the Pauli-Hamiltonian) is obtained in the non-relativistic limit. The same methods may be applied to a Dirac particle interacting with any type of external field (various meson fields, for example) and this allows one to find the proper non-relativistic Hamiltonian in each such case. Some light is cast on the question of why a Dirac electron shows some properties characteristic of a particle of finite extension by an examination of the relationship between the new and the conventional position operators.

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Journal ArticleDOI

Negative energy states in relativistic quantum chemistry

TL;DR: The role of negative energy states in relativistic quantum chemistry is discussed in this article, where the negative states must be included in a sum over states formula that arises for second-order properties.
Journal ArticleDOI

Sur une transformation de Cayley généralisant les transformations de Foldy-Woathuysen et de Cini-Touschek

TL;DR: In this article, Cayley et al. unificare la trasformazione di Foldy-Wouthuysen and quella di Cini-Touschek in una trasformation of Cayley.
Journal ArticleDOI

Canonical and manifestly covariant descriptions of particles with any spin

TL;DR: In this paper, a large class of linear, first-order invariant equations, including all finite-dimensional equations, are explicitly shown to admit a generalized PFWT transformation, which takes them into the canonical, or Foldy form.
Dissertation

A combined EMR and DFT study of radiation-induced defects in sucrose and glucose 1-phosphate

TL;DR: In this paper, a detailed study of radicals induced by X-ray radiation in solid sucrose (also known as common household sugar) and in the dipotassium salt of glucose 1-phosphate (K2G1P).
Journal ArticleDOI

On the Gamma Matrix Representations of SO(8) and Clifford Algebras

TL;DR: In this article, the gamma matrix representation of 28-dimensional SO(8) algebra, which contains the standard and additional spin operators, is considered, and the 64-dimensional representations of the Clifford algebras, namely,
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