Book ChapterDOI
On Transition Metal-Catalyzed Reactions of Norbornadiene and the Concept of π Complex Multicenter Processes
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In this paper, the authors focus on bicyclo[22l]heptadiene-2,5 (norbornadiene), a new versatile substrate for catalytic studies.Abstract:
Publisher Summary This chapter focuses on bicyclo[22l]heptadiene-2,5 (norbornadiene), a new versatile substrate for catalytic studies The chapter describes its transition metal-catalyzed reactions and discusses the mechanism of these reactions and the function of transition metals in catalytic processes of this kind The chemistry of norbornadiene is characterized by strain and homoconjugation Hence, the olefin undergoes a series of addition reactions that are frequently accompanied by the formation of the nortricyclene system—the direction of electrophilic attack being usually exo Transition metal complexes, such as nickel carbonyl or bisacrylonitrile nickel have been found to greatly promote the reaction of acrylonitrile with norbornadiene Norbornadiene may be carbonylated essentially under the conditions of Reppe's acrylic ester synthesisread more
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Three coordination in metal complexes
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Iron-Catalyzed Intermolecular [2π + 2π] Cycloaddition
TL;DR: Stoichiometric experiments resulted in isolation of a catalytically competent iron metallocycle intermediate, which was shown to undergo diene-induced C-C reductive elimination.
Book ChapterDOI
π-Allylnickel Intermediates in Organic Synthesis
TL;DR: In this article, a 1,3-rearrangement through a σ-allylnickel complex was proposed to explain the interconversion of the allyl groups.
Journal ArticleDOI
Cyclooligomerization with Transition Metal Catalysts
TL;DR: In this article, the broad applicability of methylene insertion reaction as a method for identifying mono-and di-methyl-substituted eight-, ten-, and twelve-membered rings is demonstrated.
References
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The Electronic Mechanism of Electrocyclic Reactions
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The Stereochemistry of the Pentacyclo[8.2.1.14,7.02,9.03,8]tetradecanes and -dienes. Norbornene and Norbornadiene Dimers
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