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Journal ArticleDOI

Operating Conditions for Lithium Recovery from Natural Brines

Ahmed Hichem Hamzaoui, +2 more
- 01 Dec 2007 - 
- Vol. 52, Iss: 12, pp 1859-1863
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TLDR
In this article, the molar ratio [Al]/[Li], stirring time, reaction temperature, and apparent pH of a gel of aluminum hydroxide prepared under the action of a strong base was investigated.
Abstract
Lithium recovery from natural brine incontestably requires the optimization of the parameters which influence such a process This process consists of trapping lithium ions by a gel of aluminum hydroxide prepared under the action of a strong base Studied parameters are molar ratio [Al]/[Li], stirring time, reaction temperature and apparent pH A systematic study was carried out varying only one parameter at a time This procedure makes it possible to fix the studied parameters in order to recover maximum Li+ This work is done first on synthetic brines, and then it was considered convenient to check the obtained result using natural brine and an equivalent synthetic brine Some differences related to lithium yield are established between the two considered brines This is due in our opinion to the impurities contained in the natural brine, especially magnesium and boron

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Citations
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Systematic review of lithium extraction from salt-lake brines via precipitation approaches

TL;DR: In this article, a review of the precipitation technology for lithium extraction and the relative mechanism proposed in literature to identify its important parameters are presented, such as dosage, pH value, temperature, and particle size of precipitate.
Journal ArticleDOI

Lithium recovery from highly concentrated solutions: Response surface methodology (RSM) process parameters optimization

TL;DR: In this paper, the combined effect of molar ratio Al/Li, pH and stirring time on lithium trapping at 25°C was investigated and optimized using response surface methodology (RSM), and the optimum values of these factors were found to be 4.7, 7.2 and 3.2 respectively.
Journal ArticleDOI

Materials for lithium recovery from salt lake brine

TL;DR: In this article, a review of Mg2+/Li+ separation materials and methods in the field of lithium recovery from salt lake brines is presented, and a comparison, analysis, and outlook of such methods are comprehensively discussed in terms of principles, mechanisms, synthesis/operation, development, and industrial applications.
Journal ArticleDOI

Adsorptive Li+ mining from liquid resources by H2TiO3: Equilibrium, kinetics, thermodynamics, and mechanisms

TL;DR: In this paper, Li + adsorption was Langmuir-type and followed pseudo-second-order rate model; thermodynamic parameters reveal its feasibility, spontaneity, and endothermicity.
Journal ArticleDOI

Synthesis of Li+ adsorbent (H2TiO3) and its adsorption properties

TL;DR: In this paper, Li2TiO3 was obtained from the acid-modified adsorbent precursor Li2O3, which was synthesized by a solid-phase reaction between TiO2 and Li2CO3.
References
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Journal ArticleDOI

Response surface methodology

TL;DR: In this article, the Response Surface Methodology (RSM) is used for scheduling and scheduling in response surface methodologies, and it is shown that it can be used in a variety of scenarios.
Journal ArticleDOI

Mechanism of formation of aluminum trihydroxide from keggin Al13 polymers

TL;DR: The mechanism of formation of layered aluminum hydroxides from aluminum chloride solution progressively neutralized by caustic soda has been studied by infrared spectroscopy, small-angle X-ray scattering, and 27Al high-resolution solid-state nuclear magnetic resonance as discussed by the authors.
Journal ArticleDOI

On the chemistry of the Keggin Al13 polymer

TL;DR: The acid-base properties of the polynuclear Al13 complex have been studied by alkalimetric titration using three different experimental methods as mentioned in this paper, and it was found that the aggregated Al13 represents an intermediate state between the dissolved polymer and the solid aluminum hydroxides.
Journal ArticleDOI

Conditions for Al13 Polymer Formation in Partially Neutralized Aluminum Solutions

TL;DR: In this article, the influence of synthesis methodology on the formation of the Al(O₄Al₁₃(OH)/Al ratio (n), neutralization rate, mixing conditions, and initial Al concentration was investigated to better establish boundary conditions for its formation.
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