Journal ArticleDOI
ortho-Hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center
TLDR
The iron-assisted hydroxylation of benzoic acid to salicylic acid by 1/H2O2 has been achieved in good yield under mild conditions and the product is a novel mononuclear iron(III) complex with a chelating salicylate.About:
This article is published in Chemical Communications.The article was published on 2005-10-24. It has received 83 citations till now. The article focuses on the topics: Hydroxylation & Benzoic acid.read more
Citations
More filters
Journal ArticleDOI
Mononuclear non-heme iron enzymes with the 2-His-1-carboxylate facial triad: recent developments in enzymology and modeling studies.
TL;DR: This critical review aims to provide a concise background on the chemistry of the mononuclear non-heme iron enzymes characterized by the 2-His-1-carboxylate facial triad and to discuss the many recent developments in the field.
Journal ArticleDOI
High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy
Aidan R. McDonald,Lawrence Que +1 more
TL;DR: In this paper, a review of the great successes in iron-oxo chemistry over the past decade is presented, detailing various efforts to obtain ironoxo complexes in high yield, and to delve into their diverse structural and spectroscopic properties.
Journal ArticleDOI
Pd(II)-Catalyzed Hydroxylation of Arenes with 1 atm of O2 or Air
Yanghui Zhang,Jin-Quan Yu +1 more
TL;DR: Pd(II)-catalyzed ortho-hydroxylation of variously substituted benzoic acids under 1 atm of O2 or air is achieved under nonacidic conditions as discussed by the authors.
Journal ArticleDOI
Direct azole amination: C-H functionalization as a new approach to biologically important heterocycles.
Alan Armstrong,James C. Collins +1 more
Journal ArticleDOI
Carboxylic Acids as Directing Groups for C−H Bond Functionalization
TL;DR: This Minireview summarizes the substantial progress made in the last few years in the development of reactions in which carboxylate groups direct C-H bond functionalizations with formation of C-C, C-O,C-N, or C-halogen bonds at specific positions.
References
More filters
Journal ArticleDOI
Ascorbic acid in aromatic hydroxylation. I. A model system for aromatic hydroxylation.
TL;DR: A large number of both normally occurring and foreign compounds of an aromatic nature are hydroxylated in the animal body to yield products with phenolic properties, the pathways by which these products are produced are poorly understood, but several may be postulated.
Journal ArticleDOI
Biomimetic nonheme iron catalysts for alkane hydroxylation
TL;DR: In this review, the efforts of the last 10 years in the development of nonheme iron catalysts are summarized and discussed.
Journal ArticleDOI
A synthetically useful, self-assembling MMO mimic system for catalytic alkene epoxidation with aqueous H2O2.
Journal ArticleDOI
Olefin cis-dihydroxylation versus epoxidation by non-heme iron catalysts: Two faces of an FeIII-OOH coin
TL;DR: It is demonstrated that olefin epoxidation and cis-dihydroxylation are different facets of the reactivity of a common Fe(III)-OOH intermediate, whose spin state can be modulated by the electronic and steric properties of the ligand environment.
Related Papers (5)
Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates.
A Predictably Selective Aliphatic C-H Oxidation Reaction for Complex Molecule Synthesis
Mark S. Chen,M. Christina White +1 more