Journal ArticleDOI
Oxidized Ruthenium Ferrocenylacetylide Complexes, [(.eta.-C5H5)L2RuCCFc]PF6 and [(.eta.-C5Me5)L2RuCCFc]PF6 (L = Phosphines). Electron-Delocalized Heterobinuclear Mixed-Valence Complexes
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This article is published in Organometallics.The article was published on 1994-05-01. It has received 83 citations till now. The article focuses on the topics: Ruthenium & Delocalized electron.read more
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Chemical Redox Agents for Organometallic Chemistry
TL;DR: 1. Advantages and disadvantages of Chemical Redox Agents, 2. Reversible vs Irreversible ET Reagents, 3. Categorization of Reagent Strength.
Journal ArticleDOI
Organometallic molecular wires and other nanoscale-sized devices: An approach using the organoiron (dppe)Cp*Fe building block
Frédéric Paul,Claude Lapinte +1 more
TL;DR: In this article, the potential that organometallic architectures consisting of two transition metal centers linked by an organic unsaturated spacer present for the study and development of new molecular wires is discussed.
Journal ArticleDOI
Electronic communication in heterobinuclear organometallic complexes through unsaturated hydrocarbon bridges
TL;DR: In this article, the authors discuss the flexibility of heterobimetallic complexes and more in general of asymmetric bimetallic species, in terms of tailoring the cooperative effects, i.e. of controlling and tuning the reactivity of one metal center by acting on the adjacent one.
Journal ArticleDOI
Allenylidene and Higher Cumulenylidene Complexes
Victorio Cadierno,José Gimeno +1 more
TL;DR: Catalytic Reactions Involving Allenylidene Complexes 3539 7.2.1.
Journal ArticleDOI
Ethynylferrocene Compounds of 1,3,5-Tribromobenzene
Herbert Fink,Nicholas J. Long,Angela J. Martin,Giuliana Opromolla,Andrew J. P. White,David J. Williams,Piero Zanello +6 more
TL;DR: The new compounds 1,3-dibromo-5-(ferrocenylethynyl)benzene (1), 1-bromo-, 3,5-bis(FERRICENYLTHynyl), and 1-3-5-tris(FERCORENYL) benzene(3) have been synthesized by palladium-catalyzed crosscoupling reactions and characterized, and the crystal structures of 1 and 3 have been determined as mentioned in this paper.
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Elemental carbon chain bridging two iron centers: syntheses and spectroscopic properties of [cp(dppe) fe-c4- fecp(dppe)]n+.cntdot.n[pf6]-. x-ray crystal structure of the mixed valence complex (n = 1)
Organometallic molecular wires and other nanoscale-sized devices: An approach using the organoiron (dppe)Cp*Fe building block
Frédéric Paul,Claude Lapinte +1 more