Journal ArticleDOI
Palladium and half sandwich ruthenium(II) complexes of selenated and tellurated benzotriazoles: Synthesis, structural aspects and catalytic applications
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TLDR
In this article, 1-(chloromethyl)-1H-benzotriazole with in situ generated nucleophiles PhSe− and ArTe− have been synthesized.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 2010-04-01. It has received 42 citations till now. The article focuses on the topics: Coupling reaction & Palladium.read more
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Half-sandwich arene ruthenium complexes: synthetic strategies and relevance in catalysis
TL;DR: Half-sandwich arene ruthenium complexes exhibit versatile chemistry, serve as excellent precursors and find potential applications in many organic transformations and their applications in catalytic organic transformations are discussed.
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Organoselenium ligands in catalysis.
TL;DR: In this review the survey of developments pertaining to the designing of such complexes, and their uses as catalysts for various organic reactions has been presented with critical analysis of present status of the subject.
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Formation and Role of Palladium Chalcogenide and Other Species in Suzuki–Miyaura and Heck C–C Coupling Reactions Catalyzed with Palladium(II) Complexes of Organochalcogen Ligands: Realities and Speculations
TL;DR: Palladium(II) complexes of organochalcogen ligands have emerged as viable alternatives to complexes of phosphine/carbene ligands for Suzuki-Miyaura and Heck C-C cross coupling reactions, as thermal stability and air and moisture sensitivity are not impediments with many of them as mentioned in this paper.
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Transfer Hydrogenation of Ketones and Catalytic Oxidation of Alcohols with Half-Sandwich Complexes of Ruthenium(II) Designed Using Benzene and Tridentate (S, N, E) Type Ligands (E = S, Se, Te)
Pradhumn Singh,Ajai K. Singh +1 more
TL;DR: In this paper, the authors have characterized 1H, 13C{1H}, 77Se{ 1H}, and 125Te{1h} NMR spectroscopy and X-ray crystallography.
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Palladium(II)-selenated Schiff base complex catalyzed Suzuki-Miyaura coupling: dependence of efficiency on alkyl chain length of ligand.
TL;DR: The new selenated Schiff bases L1-L4 which differ in the chain lengths of non-coordinating substituents and their square planar complexes have been synthesized and characterized by multinuclei NMR and the activity of 4 which has ligand L4 has been found highest.
References
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Phase annealing in SHELX-90: direct methods for larger structures
TL;DR: In this article, a phase annealing method, related to the simulated-annealing approach in other optimization problems, is proposed and it is shown that it can result in an improvement of up to an order of magnitude in the chances of solving large structures at atomic resolution.
Journal ArticleDOI
Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more
TL;DR: In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.
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Palladium-Catalyzed Coupling Reactions of Aryl Chlorides
Adam F. Littke,Gregory C. Fu +1 more
TL;DR: This review summarizes both the seminal early work and the exciting recent developments in the area of palladium-catalyzed couplings of aryl chlorides.
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Organometallic chemistry, biology and medicine: ruthenium arene anticancer complexes
TL;DR: Initial studies on amino acids and nucleotides suggest that kinetic and thermodynamic control over a wide spectrum of reactions of Ru(II) arene complexes with biomolecules can be achieved.
Journal ArticleDOI
The development of palladium catalysts for CC and Cheteroatom bond forming reactions of aryl chloride substrates
TL;DR: In this paper, the design and application of new homogeneous palladium catalysts for the formation of C C and C heteroatom bonds from aryl chloride substrates is reviewed.
Related Papers (5)
Palladium(II), platinum(II), ruthenium(II) and mercury(II) complexes of potentially tridentate Schiff base ligands of (E, N, O) type (E = S, Se, Te): Synthesis, crystal structures and applications in Heck and Suzuki coupling reactions
Transfer Hydrogenation of Ketones and Catalytic Oxidation of Alcohols with Half-Sandwich Complexes of Ruthenium(II) Designed Using Benzene and Tridentate (S, N, E) Type Ligands (E = S, Se, Te)
Pradhumn Singh,Ajai K. Singh +1 more