Journal ArticleDOI
Palladium-Catalyzed Arylation of Polar Organometallics Mediated by 9-Methoxy-9-Borabicyclo[3.3.1]nonane: Suzuki Reactions of Extended Scope
Alois Fürstner,Günter Seidel +1 more
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TLDR
In this paper, an alternative way for performing Suzuki reactions is presented, where the necessary borate which is the actual nucleophile in these palladium catalyzed C-C-bond formations is prepared from 9-methoxy-9-bora-bicyclo[3.3]nonane (9-OMe- 9-BBN) and a polar organometallic reagent RM, and not as usually from a borane and a base.About:
This article is published in Tetrahedron.The article was published on 1995-10-09. It has received 113 citations till now. The article focuses on the topics: 9-Borabicyclo[3.3.1]nonane & Suzuki reaction.read more
Citations
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Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995–1998
TL;DR: The palladium-catalyzed cross-coupling reaction between organoboron compounds and organic halides or triflates provides a powerful and general methodology for the formation of carbon-carbon bonds as discussed by the authors.
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Recent applications of the Suzuki–Miyaura cross-coupling reaction in organic synthesis
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Cross-coupling reactions of organoboranes: an easy way to construct C-C bonds (Nobel Lecture).
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Selection of boron reagents for Suzuki-Miyaura coupling
TL;DR: This review analyses the seven main classes of boron reagent and evaluates the general physical and chemical properties of each class with special emphasis on the currently understood mechanisms of transmetalation.
References
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The Palladium-Catalyzed Cross-Coupling Reaction of Phenylboronic Acid with Haloarenes in the Presence of Bases
TL;DR: The transition metal-catalyzed reactions of organometallics with organic halides have been extensively studied to prove a new approach to selective formation of carbon-carbon bonds as mentioned in this paper.
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Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II): an effective catalyst for cross-coupling of secondary and primary alkyl Grignard and alkylzinc reagents with organic halides
TL;DR: Etude d'une trentaine de reactions, avec des complexes de Ni au Pd pour le couplage des bromo-benzene, -styrene, -anisole, -toluene avec le chlorure de butylmagnesium as discussed by the authors.
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Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more