Journal ArticleDOI
Phase transitions at electrode interfaces
TLDR
In this article, a statistical model of the adsorption of ions at the electrode interface is presented, which is equivalent to a two-dimensional lattice gas and is applied to the case of the underpotential deposition of copper onto gold.About:
This article is published in Electrochimica Acta.The article was published on 1996-07-10. It has received 54 citations till now. The article focuses on the topics: Hexagonal lattice & Underpotential deposition.read more
Citations
More filters
Journal ArticleDOI
Underpotential deposition at single crystal surfaces of Au, Pt, Ag and other materials
Journal ArticleDOI
Electrochemical dissolution of surface alloys in acids: Thermodynamic trends from first-principles calculations
TL;DR: In this article, a simple procedure is introduced to use periodic density functional theory calculations to estimate trends in the thermodynamics of surface alloy dissolution in acidic media, and the dissolution potentials for solute metal atoms embedded in the surface layer of various host metals are calculated.
Journal ArticleDOI
Cyclic voltammograms for H on Pt(111) and Pt(100) from first principles.
Gustav Karlberg,Thomas F. Jaramillo,Egill Skúlason,Jan Rossmeisl,Thomas Bligaard,Jens K. Nørskov +5 more
TL;DR: The cyclic voltammogram for H on Pt(111) and Pt(100), based solely on density functional theory calculations and standard molecular tables, is derived, providing a direct link between surface science and electrochemistry.
Journal ArticleDOI
Voltammetric Properties of the Reductive Desorption of Alkanethiol Self-Assembled Monolayers from a Metal Surface
TL;DR: In this article, a linear-scan voltammogram for the reductive desorption of alkanethiol self-assembled monolayers (SAMs) from a gold surface in an aqueous alkaline solution exhibits intriguing features: the narrow full width at half-maximum (fwhm) of the peak, e.g., 20 mV for dodecanethiol SAMs, the saturation of fwhm in the SAM composed of long-chain alkarnethiols, an asymmetric shape, the shift of peak potential with increasing the
Journal ArticleDOI
A lattice-gas model for halide adsorption on single-crystal electrodes
TL;DR: In this article, a lattice-gas model for the adsorption of halides on single-crystal electrodes is described, and the model reproduces the order-disorder transition observed experimentally, and how the long-ranged interactions influence the properties of this phase transition is discussed.
References
More filters
Book
Phase Transitions and Critical Phenomena
TL;DR: The field of phase transitions and critical phenomena continues to be active in research, producing a steady stream of interesting and fruitful results as discussed by the authors, and the major aim of this serial is to provide review articles that can serve as standard references for research workers in the field.
Book
Exactly solved models in statistical mechanics
TL;DR: In this article, exactly solved models of statistical mechanics are discussed. But they do not consider exactly solvable models in statistical mechanics, which is a special issue in the statistical mechanics of the classical two-dimensional faculty of science.
Journal ArticleDOI
Kinetics of Phase Change. II Transformation‐Time Relations for Random Distribution of Nuclei
TL;DR: In this article, a relation between the actual transformed volume V and a related extended volume V1 ex is derived upon statistical considerations, and a rough approximation to this relation is shown to lead, under the proper conditions, to the empirical formula of Austin and Rickett.
Journal ArticleDOI
Granulation, Phase Change, and Microstructure Kinetics of Phase Change. III
TL;DR: In this paper, a comprehensive description of the phenomena of phase change may be summarized in Phase Change, Grain Number and Microstructure Formulas or Diagrams, giving, respectively, the transformed volume, grain, and microstructure densities as a function of time, temperature, and other variables.
Book
Introduction to Phase Transitions and Critical Phenomena
H. Eugene Stanley,Guenter Ahlers +1 more
TL;DR: In this article, the authors present a paperback edition of a distinguished book, originally published by Clarendon Press in 1971, which is at the level at which a graduate student who has studied condensed matter physics can begin to comprehend the nature of phase transitions, which involve the transformation of one state of matter into another.
Related Papers (5)
A model for sequential first-order phase transitions occurring in the underpotential deposition of metals
Dale A. Huckaby,Lesser Blum +1 more