Journal ArticleDOI
Phosphine complexes of the early metals and the lanthanoids
TLDR
The coordination chemistry of the mixed-donor tridentate ligand -N(SiMezCH2PR2)2 with the early transition metals of groups 3 and 4 and the lanthanide elements is presented in this paper.Abstract:
The coordination chemistry of the mixed-donor tridentate ligand -N(SiMezCH2PR2)2 with the early transition metals of groups 3 and 4 and the lanthanide elements will be presented. This ancillary ligand has allowed for the formation of phosphine complexes of these hard elements which has in turn induced new reactivity patterns for hydrocarbyl ligands. The stability and reactivity of metal complexes are a function of both the position of the metal in the periodic table and the nature of the ligands. While the former provides for diverse chemical reactivity, it isread more
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Implementation of Cooperative Designs in Polarized Transition Metal Systems—Significance for Bond Activation and Catalysis
Basujit Chatterjee,Basujit Chatterjee,Wei-Chieh Chang,Wei-Chieh Chang,Soumyashree Jena,Soumyashree Jena,Christophe Werlé,Christophe Werlé +7 more
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Journal ArticleDOI
Different Schiff Bases—Structure, Importance and Classification
TL;DR: Schiff bases are a vast group of compounds characterized by the presence of a double bond linking carbon and nitrogen atoms, the versatility of which is generated in the many ways to combine a variety of alkyl or aryl substituents as mentioned in this paper .
Journal ArticleDOI
Synthesis, structure and fluxional behavior of [ν5-C5H3-1,3-(SiMe2CH2PPri202[ZrCl3−x Rx(R = Me, CH2Ph, x = 0, 1, 3)
Journal ArticleDOI
Synthesis and Characterization of Four- and Five-Coordinate Organoaluminum Complexes Incorporating the Amido Diphosphine Ligand System N(SiMe2CH2PPri2)2
TL;DR: In this article, the preparation of new four and five-coordinate aluminum amido diphosphine complexes was reported and the reaction of the potentially tridentate ligand precursor LiN(SiMe2CH2PPri2)2 with AlCl3 in tolu...
Journal ArticleDOI
Lanthanide‐Mediated Ligand Transfer Reactions—A Route to Late Transition Metal Bisamido Complexes
TL;DR: Treatment of one equivalent of 1 or 2 with two equivalents of [(cod)CuCl] results in the formation of the polycyclic tetranuclear complex [[O(SiMe2Ap)2]2Cu4] (8).