Book ChapterDOI
Phosphorus phosphorus compounds with the coordination number 4
H.D. Ebert
- pp 90-110
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The article was published on 1977-01-01. It has received 0 citations till now. The article focuses on the topics: Phosphorus.read more
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Journal ArticleDOI
Pseudochalkogenverbindungen. X. Die Synthese von Cyanamidophosphaten aus Phosphoroxidchloriden
H. Köhler,U. Pössel +1 more
TL;DR: Cyanamidophosphoroxidchloride POC13 and P2O3CI4 fuhren zu den cyanamido-mono-bzw -diphosphate P04−n(NCN)n3− (n = 1, 2) and P207−n (NCN 4−n)n4−n−n
Journal ArticleDOI
Preparation and Fluxional Behavior of New Rhodiacyclopentadiene Complexes Containing Trifluorophosphine
Journal ArticleDOI
Perfluormethyl-element-liganden XIII [1]: ein neuer weg zu zweikernkomplexen des typs M2(CO)8E(CF3)2X (M = Mn, Re)
TL;DR: In this paper, a three-step reaction path starting with the cleavage of E 2 (CF 3 ) 4 followed by the subtitution of a cis-CO group in the M(CO) 5 X component by M 2 (CO) 8 [E(CF 3 ] 2 ] 2, which is however not formed by the partial replacement of X by E(CF3 ) 2 since this reaction requires temperatures above 120°C.
Journal ArticleDOI
Preparation and nuclear magnetic resonance spectra of the chloro-monofluorocyclophosphazenes
TL;DR: The cyclic chlorophosphazenes NnPnCl2n(n= 3-6) were fluorinated by a mixture of SbF3 and SbCl5 to give either the monofluoro-compound or, depending on the reagent ratio, mixtures of non-geminal chloride fluorides as discussed by the authors.
Journal ArticleDOI
The Mechanism of the Hydrolysis of Condensed Phosphates. IV. The Hydrolysis of Pyro-, Tripoly-, Trimeta-, and Tetrametaphosphates in Aqueous Organic Solvents
TL;DR: In this paper, the nucleophilicity of the water molecule in the aqueous organic solutions may increase on account of the interaction of water molecule with the organic molecules, and the initial concentration of the phosphates was 0.025 mol/l.