Journal ArticleDOI
Photoelectron spectroscopy of coordination compounds. II. Palladium complexes
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This article is published in Inorganic Chemistry.The article was published on 1972-02-01. It has received 206 citations till now. The article focuses on the topics: Coordination complex & Palladium.read more
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Palladium Nanoparticles on Graphite Oxide and Its Functionalized Graphene Derivatives as Highly Active Catalysts for the Suzuki−Miyaura Coupling Reaction
TL;DR: In contrast to the conventional Pd/C catalyst, graphite oxide and graphene-based catalysts gave much higher activities with turnover frequencies exceeding 39,000 h(-1), accompanied by very low palladium leaching (<1 ppm).
PatentDOI
Layered double hydroxides supported nanopalladium catalysts for Heck-, Suzuki, Sonogashira-, and Stille type coupling reactions of haloarenes
Boyapati M. Choudary,Madhi Sateesh Naidu,Sreenivasa Naidu,Mannepalli Lakshmi Kantam,Bojja Sreedhar +4 more
TL;DR: In this article, a reusable heterogeneous nanopalladium (0) catalysts were used for coupling products by C-C bond formation reaction of haloarenes that include unreactive chloroarenes in the presence of base.
Journal ArticleDOI
Synthesis and mechanistic study of palladium nanobars and nanorods.
TL;DR: It is found that one-dimensional growth could be induced and maintained through an interplay of the following processes: speedy reduction of the precursor to ensure prompt addition of atoms to the seed; chemisorption of bromide on the seed to promote the formation of {100} and {110} facets.
Journal ArticleDOI
An XPS study of metal-support interactions on Pd/SiO2 and Pd/La2O3
TL;DR: In this paper, the electronic properties of palladium supported on SiO 2 and La 2 O 3 were investigated by X-ray photoelectron spectroscopy, showing that Pd is more electronegative than zero-valent Pd alone.
Journal ArticleDOI
X-ray photoelectron spectra of cobalt compounds
TL;DR: The X-ray photoelectron spectra of a variety of cobalt(II) and cobalt-III complexes have been investigated in this paper, showing that the 2p, 3s and 3p peaks of the high-spin cobalt (II) compounds are dominated by shake-up processes, whereas those of the 3s, 3p and 3s levels arise largely from multiplet splitting of the levels.