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Journal ArticleDOI

Photoinduced Electron-Transfer Reactions. Radical Cations of the 1,2-Diphenylcyclopropanes

Heinz D. Roth, +1 more
- 01 Dec 1980 - 
- Vol. 102, Iss: 27, pp 7956-7958
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This article is published in Journal of the American Chemical Society.The article was published on 1980-12-01. It has received 39 citations till now. The article focuses on the topics: Photoinduced electron transfer.

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Journal ArticleDOI

Distonic radical cations in gaseous and condensed phase

TL;DR: In this paper, the authors demontre que les radicaux cationiques CH 3 OH +, CH 3 NH 2 + and CH 3 ClH + ont des isomeres stables.
Journal ArticleDOI

Aminofluorination of Cyclopropanes: A Multifold Approach through a Common, Catalytically Generated Intermediate

TL;DR: Calculations suggest that solvent may play an important role in the cyclopropane ring-opening step, and transient-absorption experiments have allowed direct spectroscopic observation of radical ion intermediates and have provided kinetic support for chain propagation.
Book ChapterDOI

The Chemistry of Excited Complexes: a Survey of Reactions

TL;DR: In this article, the authors focus on the chemistry of excited complexes and the maximum rate for the process is determined by the rate constant for diffusion control in the solvent employed, which is a function of the number of collisions that must occur within the lifetime of the excited state.
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