Journal ArticleDOI
Rate of homogeneous nucleation in alkali disilicate glasses
Kazumasa Matusita,Megumi Tashiro +1 more
TLDR
In this article, the authors measured the rate of crystal nucleation in alkali disilicate glasses by counting the number of crystals under an optical microscope and measured the viscosities of these glasses by the method of beam bending and penetration using the data of rate of nucleation and viscosity obtained in the present study and data of free energy measured by Takahashi and Yoshio.Abstract:
Rates of crystal nucleation in alkali disilicate glasses were measured by counting the number of crystals under an optical microscope The viscosities of these glasses were measured by the method of beam-bending and penetration Using the data of rate of nucleation and viscosity obtained in the present study and the data of free energy measured by Takahashi and Yoshio, crystal-glass interfacial energies for alkali disilicate systems were estimated on the basis of homogeneous nucleation theory as follows: 196 erg/cm2 for Li2O·2SiO2, 126–144 erg/cm2 for Na2O·2SiO2 and 88–104 erg/cm2 for K2O·2SiO2 The effects of the viscosity of glass, the free energy difference between crystal and glass and crystal-glass interfacial energy on the rate of nucleation were discussed, and the remarkably higher rate of crystal nucleation in the Li2O·2SiO2 glass was attributed to the larger free energy differenceread more
Citations
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Book ChapterDOI
Crystal Nucleation in Liquids and Glasses
TL;DR: In this paper, the authors focus on measurements and theories pertaining to homogeneous nucleation under cooled liquids and glasses that transform to phases of the same composition, and incorporate time-dependent nucleation and the interface kinetics into the field-theoretic approaches to give theories that are as widely applicable and, hence, testable as the classical theory.
Journal ArticleDOI
Glass formation criterion for various glass-forming systems
Zhaoping Lu,C.T. Liu +1 more
TL;DR: A conceptual approach to evaluate glass-forming ability for variousGlass-forming systems has been proposed from a physical metallurgy point of view and this approach was confirmed and validated by experimental data in various glass-formation systems including oxide glasses, cryoprotectants, and metallic glasses.
Journal ArticleDOI
Kinetics of non-isothermal crystallization process and activation energy for crystal growth in amorphous materials
TL;DR: In this article, an equation expressing the volume fraction,x, of crystals precipitating in a glass heated at a constant rate, α, was derived and the validity and usefulness of this equation was ascertained by applying it to a Li2O·2SiO2 glass.
Journal ArticleDOI
Crystal nucleation and growth of indomethacin polymorphs from the amorphous state
Vlassios Andronis,George Zografi +1 more
TL;DR: The effect of temperature on the overall crystallization and the crystal nucleation and growth rates of indomethacin polymorphs from the amorphous state were determined in this article.
Journal ArticleDOI
Phase transformation and growth of mullite in kaolin ceramics
TL;DR: The phase transformation and growth of mullite (3Al 2 O 3 ·2SiO 2 ) in kaolin ceramics have been investigated using X-ray diffractometer, transmission electron microscope, select area electron diffractometers, energy dispersion spectrometer and differential thermal analysis as mentioned in this paper.
References
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Journal ArticleDOI
A theory of surface tension of solids—I application to metals
TL;DR: In this article, a theory is developed which allows one to calculate the surface tension of nonionic solids (metals and nonmetals) from the arrangement of their next neighbors, from the heat of fusion, and from the surface tensor of the liquid at the melting point.
Journal ArticleDOI
Experimental Evaluation of Beam-Bending Method of Determining Glass Viscosities in the Range 108 to 1015 Poises
TL;DR: In this paper, the beam-bending method was used to determine the viscosity of a glass by the viscous bending of a simple beam, compared with the fiber-elongation technique.
Journal ArticleDOI
Crystallization and Melting Kinetics of Cristobalite
TL;DR: In this paper, internal crystallization in vitreous silica was measured and the kinetics of crystallization and melting of cristobalite were determined near the melting point, showing that both processes followed linear growth kinetics and could be completely represented by the equation μ=AΔT/η.
Journal ArticleDOI
Nucleation and Growth of Sodium Disilicate Crystals in Sodium Disilicate Glass
William D. Scott,Joseph A. Pask +1 more
TL;DR: In this article, a high-temperature microscope for use with transmitted or reflected light up to × 400 magnification and up to 1400°C was constructed, and linear growth rates of α and β sodium disilicate crystals were measured from 600° to 870° C.
Journal ArticleDOI
A Penetration Viscometer for Determining Viscosity of Glass
TL;DR: In this article, an apparatus was constructed for determining the viscosities of small flat pieces of glass from the rate of penetration of a cylindrical indenter into the glass, and the relation between the penetration depth and viscosity of glass was determined with this viscometer.