Journal ArticleDOI
Recent developments in the organometallic chemistry of phospha-alkynes, RCP
TLDR
Recent developments in synthetic, structural and spectroscopic aspects of organometallic compounds derived from phospha-alkynes are reviewed in this article, where the authors present a review of the main aspects of these compounds.About:
This article is published in Coordination Chemistry Reviews.The article was published on 1995-11-01. It has received 108 citations till now. The article focuses on the topics: Organometallic chemistry & Group 2 organometallic chemistry.read more
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Phosphaalkene, phospholyl and phosphinine ligands: New tools in coordination chemistry and catalysis
TL;DR: A review of low coordinate phosphorus ligands featuring P=C double bonds can be found in this article, where the most significant developments are presented and discussed for each class of ligands.
Journal ArticleDOI
P4 Activation by Late-Transition Metal Complexes†‡
TL;DR: The coordination chemistry of white phosphorus is nowadays a mature discipline, which during the last four decades has reached a deep understanding of the mechanisms governing the metal-mediated activation of this unique and highly reactive molecule.
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Transition metals in phosphinine chemistry
Pascal Le Floch,François Mathey +1 more
TL;DR: The implication of transition metals in phosphinine chemistry is reviewed in this article, where three different topics are examined: syntheses in which phosphinines are formed using a metal-mediated approach, transformations of preformed syntheses induced by metals, and the role of transition metal in coordination chemistry.
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A niobaziridine hydride system for white phosphorus or dinitrogen activation and N- or P-atom transfer
TL;DR: In a fashion analogous to the aforementioned phosphaalkyne synthesis, acid chlorides are transformed upon reaction with the niobium nitride anion into corresponding nitrogen-15 labeled organic nitriles, as the oxoniobium(v) byproduct can be recycled in high yield to the title niobaziridine hydride complex.
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Journal ArticleDOI
Coordination chemistry of compounds containing phosphorus-carbon multiple bonds
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Phosphaalkynes—Syntheses, Reactions, Coordination Behavior [New Synthetic Methods (73)]†
Manfred Regitz,Paul Binger +1 more
TL;DR: The use of low-coordination phosphorus compounds in the synthesis of polycyclic compounds has been studied in the last few years as mentioned in this paper, with the use of phosphaalkynes as ligand systems in complex chemistry and their cyclooligomerization with organometallic reagents.
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The chemistry of phospha- and polyphosphacyclopentadienide anions
TL;DR: The synthesis, structural and spectroscopic features, organic and coordination chemistry of phospholide and polyphospholide anions are comprehensively reviewed in this article, where the synthesis and coordination of anions is discussed.