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Journal ArticleDOI

Restricted rotation in hexaarylbenzenes

Devens Gust
- 01 Jan 1977 - 
- Vol. 99, Iss: 21, pp 6980-6982
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This article is published in Journal of the American Chemical Society.The article was published on 1977-01-01. It has received 63 citations till now. The article focuses on the topics: Rotation.

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Journal ArticleDOI

Design of Collective Motions from Synthetic Molecular Switches, Rotors, and Motors

TL;DR: This review provides an in-depth look at the intermolecular couplings used to physically connect a number of artificial mechanically active molecular units such as photochromic molecular switches, nanomachines based on mechanical bonds, molecular rotors, and light-powered rotary motors.
Journal ArticleDOI

Determination of the pKa of Ethyl Acetate: Brønsted Correlation for Deprotonation of a Simple Oxygen Ester in Aqueous Solution

TL;DR: The rate constants for deprotonation of ethyl acetate by 3-substituted quinuclidines are correlated by β = 1.09 ± 0.05 as mentioned in this paper.
Book ChapterDOI

Bulky or Supracyclopentadienyl Derivatives in Organometallic Chemistry

TL;DR: In this article, the authors focus on supracyclopentadienyl derivatives in organometallic chemistry and present a large number of them as ligands in metal complexes.
Journal ArticleDOI

Hexaarylbenzene: Evolution of Properties and Applications of Multitalented Scaffold

TL;DR: Detailed attention is given to the pioneering work based on synthetic optimization of different HAB cores, elaborated study of their crystal engineering, various interesting applications of HAB derivatives, and future possibilities and capabilities of this still underexplored scaffold.
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