Journal ArticleDOI
Rhenium octahedral clusters: Characterization of Re6Se4Cl10 and the parent compound Re6Br10
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TLDR
The first member of the new series Re6Se4+xCl10 ·x−Re6,Se4Cl10 is described in this article, where the main feature of the single-crystal structure determination is the occurrence of octahedral Re6 clusters included in Re6S4Br10, units.About:
This article is published in Materials Letters.The article was published on 1985-04-01. It has received 38 citations till now. The article focuses on the topics: Rhenium.read more
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Chemistry of hexanuclear rhenium chalcohalide clusters.
Journal ArticleDOI
A Solid-State Route to Molecular Clusters: Access to the Solution Chemistry of [Re6Q8]2+ (Q = S, Se) Core-Containing Clusters via Dimensional Reduction
TL;DR: By replacing single metal centers with multinuclear cluster cores, this dimensional reduction approach is extended to cluster-containing frameworks and obtained display frameworks of reduced connectedness and dimensionality.
Journal ArticleDOI
Cocrystallized Mixtures and Multiple Geometries: Syntheses, Structures, and NMR Spectroscopy of the Re6 Clusters [NMe4]4[Re6(Te8-nSen)(CN)6] (n = 0−8)
TL;DR: The mixed tellurium/selenium Re6 clusters [NMe4]4[Re6(Te8-nSen)(CN)6] (n = 0−8) have been prepared from the reactions of Re6Te15 with the appropriate stoichiometry of NaCN and Se at 600 °C, followed by cation exchange with NMe4Br as discussed by the authors.
Journal ArticleDOI
Cluster valenzelektronenarmer Metalle – Strukturen, Bindung, Eigenschaften
TL;DR: In this paper, the Verbindungs- und Strukturenvielfalt bei metallreichen Systemen valenzelektronenarmer Metalle unter einem einheitlichen Blickwinkel zu ordnen.
References
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Journal ArticleDOI
Metall‐Metall‐Bindungen bei niederen Halogeniden, Oxyden und Oxydhalogeniden schwerer Übergangsmetalle Thermochemische und strukturelle Prinzipien
TL;DR: In this article, bei den niederen Halogeniden des Niobs und Tantals Eigentumlichkeiten im Hinblick auf Stochiometrie, Homogenitatsgebiete und Bindungsverhaltnisse erkennen.
Journal ArticleDOI
Electronic structure of Chevrel-phase high-critical-field superconductors
O. K. Andersen,W. Klose,H. Nohl +2 more
TL;DR: In this article, the authors studied the band structures of Chevrel-phase molybdenum chalcogenides, and presented level schemes, computed for a range of Mo and $X$ potentials, for three compounds.
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Molybdenum Chalcogenides: Clusters, Chains, and Extended Solids. The Approach to Bonding in Three Dimensions
Timothy Hughbanks,Roald Hoffmann +1 more
TL;DR: In this article, a combined molecular orbital and crystal orbital analysis of systems containing Mo/sub 3n/X/Sub 3n + 2/ (n = 2,3,4,infinity; X=S,Se,Te) units is presented.
Journal ArticleDOI
Beziehungen zwischen Bindungslängen und Bindungsstärken in Oxidstrukturen
TL;DR: The vond valencev, which is a measure for bond strengths, was estimated byPauling, 19291, as the ratio of charge to coordination number of the cation as discussed by the authors.
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