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Journal ArticleDOI

Second virial coefficients of alkali vapours

A. B. Sannigrahi, +2 more
- 01 Mar 1976 - 
- Vol. 31, Iss: 3, pp 963-970
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This article is published in Molecular Physics.The article was published on 1976-03-01. It has received 10 citations till now. The article focuses on the topics: Virial coefficient & Vapours.

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Citations
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A simple semi-empirical approach to the intermolecular potential of van der Waals systems

TL;DR: In this paper, a simple potential model for the evaluation of isotropic pairwise interaction energies is proposed and used to predict the lowest triplet state curve of all alkali-alkali interactions.
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Thermophysical Properties of Alkali Metal Vapours, Part I — Theoretical Calculation of the Properties of Monatomic Systems

TL;DR: In this paper, the second virial coefficients, self-diffusion, viscosity and thermal conductivity of monatomic alkali metal vapours, lithium, sodium, potassium, cesium and rubidium are presented.
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Clustering and some other physical effects of van der Waals potentials

TL;DR: In this article, an improved analytic equation-of-state for the van der Waals model is presented based on a simple but accurate semi-empirical expression for the hard sphere reference fluid and Andrews' development for the attractive perturbation.
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An analytical equation of state for molten alkali metals

TL;DR: In this article, the authors brought the molten alkali metals into the scope of a new statistical mechanical equation of state that is known to satisfy normal fluids over the whole range of temperature.
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Equation of State for Molten Alkali Metal Alloys

TL;DR: In this article, the liquid density of binary alloys of Na-K and K-Cs over the whole range of concentrations and that of a ternary molten eutectic of Na−K-Cs from the freezing point up to several hundred degrees above the boiling point are presented.
References
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Book

Molecular theory of gases and liquids

TL;DR: Molecular theory of gases and liquids as mentioned in this paper, molecular theory of gas and liquids, Molecular theory of liquid and gas, molecular theories of gases, and liquid theory of liquids, مرکز
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Diatomic Molecules According to the Wave Mechanics. II. Vibrational Levels

TL;DR: In this paper, an exact solution for the Schroedinger equation representing the motions of the nuclei in a diatomic molecule, when the potential energy function is assumed to be of a form similar to those required by Heitler and London and others, was obtained.
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On the determination of molecular fields. —II. From the equation of state of a gas

TL;DR: In this paper, it was shown that a molecular model of the same type will also explain available experimental data concerning the equation of state of a gas, and if so, whether the results so obtained, when taken in conjunction with those obtained from viscosity, will definitely fix the molecular field.