Journal ArticleDOI
Semiconductor-metal transition upon intercalation in LixZrSe2
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In this paper, the authors present a set of experimental data on the Li x ZrSe 2 system as a function of x, including X ray, electrochemical, conductivity, NMR and EPR measurements.About:
This article is published in Solid State Ionics.The article was published on 1981-10-01. It has received 34 citations till now. The article focuses on the topics: Electron paramagnetic resonance & Diamagnetism.read more
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Journal ArticleDOI
Electronic Transfer and Phase Transitions in Cationic Intercalation Chemistry in Low-Dimensional Chalcogenides
TL;DR: In this article, it was shown that the electronic transfer plays an essential role concerning the ability to intercalate and also governs the phase transitions that can be observed, which can be also related to a strong ion-electron coupling.
Journal ArticleDOI
X-ray absorption spectroscopy of the first-row transition-metal intercalates of layered transition-metal disulfides
TL;DR: In this article, the authors measured the X-ray absorption spectra of the first-row transition-metal intercalates denoted by M 1/3 TS 2 (M = Ti, V, Cr, Mn, Fe, Co, Ni; T = T, Zr,V, Nb) and found that the appearance as a whole was not greatly affected by intercalation.
Book ChapterDOI
Influence of the zirconium diselenide stoichiometry on its behaviour upon lithium intercalation
TL;DR: Zirconium diselenide belongs to the IVB group transition metal dichalcogenides which have lamellar structures and easily intercalate metals and molecules from optical measurements (Lee et al, 1969) it appears as a semiconductor with a 12 eV energy gap as mentioned in this paper.
Journal ArticleDOI
The Electronic Transfer and the Formation of Cationic Intercalation Compounds
TL;DR: In this paper, the relationship between chemical reactivity and the electronic structure of the host was investigated and a special attention was paid to the nature of redox centers involved in the intercalation process.
Journal ArticleDOI
In-Situ NMR Studies of Lithium Intercalated Electrode Materials Inside All-Solid-State Electrochemical Cells
TL;DR: In this paper, preliminary results of in-situ NMR studies on lithium intercalated electrode materials in all solid state electro-chemical cells are presented, and the design of the cells is briefly presented and their results are compared with previous studies on compounds chemically Intercalated with the n-butyllithium technique.
References
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Journal ArticleDOI
Lithium intercalation via n-Butyllithium of the layered transition metal dichalcogenides
TL;DR: In this paper, Butyllithium in hexane solution serves as an excellent reagent to effect the intercalation of lithium into the Group IVb and Vb layered dichalcogenides.
Journal ArticleDOI
On the optical properties of some layer compounds
TL;DR: In this paper, the optical properties of single crystals near the fundamental absorption edge of the following layer compounds: Sn Sx Se2−x (where 0 ⩽ x⩽ 2), ZrS2, ZrSe2, TiS2 and CdI2.
Journal ArticleDOI
Lithium intercalation complexes of layered transition metal dichalcogenides: An NMR survey of physical properties
TL;DR: In this paper, NMR studies of lithium intercalation complexes of layered disulfides and diselenides of Group IVb and Vb transition metals establish that the inclusion of a guest lithium atom between the host dichalcogenide layers is accompanied by the donation of approximately one electron to the host.
Journal ArticleDOI
NMR investigation of the layered transition metal phosphorus trichalcogenides and the intercalation compounds LixNiPS3
TL;DR: In this paper, the magnetic properties of the transition metal phosphorus trichalcogenides MPX3 and their modification as a function of intercalation in the compounds LixNiPS3 were studied.