Journal ArticleDOI
Simultaneous spectrophotometric determination of cyanide and thiocyanate after separation on a melamine-formaldehyde resin
TLDR
The developed chlorine-o-tolidine method is relatively inexpensive and less laborious than the standard (Spectroquant) procedure, and insensitive to the common interferent, cyanate (CNO(-)).About:
This article is published in Talanta.The article was published on 2000-11-01. It has received 31 citations till now. The article focuses on the topics: Cyanide & Thiocyanate.read more
Citations
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Journal ArticleDOI
Simultaneous kinetic spectrophotometric determination of cyanide and thiocyanate using the partial least squares (PLS) regression
TL;DR: The proposed partial least squares (PLS-1) calibration model based on spectrophotometric measurement was successfully applied to the simultaneous determination of cyanide and thiocyanate in water samples and showed that simultaneous determination could be performed in the range 10.0-900.0 and 50.
Journal ArticleDOI
Spectrophotometric determination of aqueous cyanide using a revised phenolphthalin method
TL;DR: The revised phenolphthalin method for cyanide analysis was found to have suitably fast kinetics, a linear dynamic range of 0.01-3.0 ppm cyanide, and a detection limit of 5 ppb.
Journal ArticleDOI
Solvent extraction flow-injection manifold for the simultaneous spectrophotometric determination of free cyanide and thiocyanate ions based upon on-line masking of cyanides by formaldehyde
TL;DR: In this article, a sensitive solvent extraction flow-injection (FI) method was proposed for the simultaneous spectrophotometric determination of free cyanide and thiocyanate in human saliva and pralidoxime solutions.
Journal ArticleDOI
Determination of Thiocyanate within Physiological Fluids and Environmental Samples: Current Practice and Future Trends
TL;DR: This review is intended not only to provide a comparison of the different methods employed, but also to make it possible for the interested reader to quickly find developments and relevant work that have transpired over the past 10 years.
Journal ArticleDOI
The reaction of HOCl and cyanocobalamin: Corrin destruction and the liberation of cyanogen chloride
Husam M. Abu-Soud,Dhiman Maitra,Jaeman Byun,Carlos Eduardo A. Souza,Jashoman Banerjee,Ghassan M. Saed,Michael P. Diamond,Peter R. Andreana,Subramaniam Pennathur +8 more
TL;DR: It is demonstrated that although Cobl can be an excellent antioxidant, exposure to high levels of HOCl can overcome the beneficial effects of Cobl and generate proinflammatory reaction products, the first report of the generation of toxic molecular products through the interaction of CobL with HOCl.
References
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Book
Statistics for Analytical Chemistry
TL;DR: In this article, the authors present a summary of statistical tests for classical analysis, including errors in classical analysis - Statistics of Repeated Measurements and Statistical Tests for Instrumental Analysis.
Journal ArticleDOI
Stable reagents for the colorimetric determination of cyanide by modified Koenig reactions
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Aerobic biodegradation of thiocyanate
TL;DR: Neither thiocyanate nor cyanate inhibited the aerobic removal and assimilation of organic compounds simulating typical municipal wastewaters, however, partial inhibition of nitrification, especially the conversion of nitrite to nitrate, was observed, and was attributed to thiOCyanate and/or free ammonia.
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Cyanide Determination Using an Amperometric Biosensor Based on Cytochrome Oxidase Inhibition
TL;DR: An amperometric reagentless biosensor, based on a carbon paste electrode (CPE) modified by asolectin, Cytochrome c, and cytochrome oxidase, is described for the sensitive determination of cyanide, allowing cyanide determination for more than 2 months using the same probe.
Related Papers (5)
Simultaneous determination of trace amounts of free cyanide and thiocyanate by a stopped-flow spectrophotometric method
Bianting Sun,Barry N. Noller +1 more