Journal ArticleDOI
Solvatochromically based solvent-selectivity triangle
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In this paper, a classification of common solvents according to their dipolarity and hydrogen-bonding acidity and basicity has been developed, based on the Kamlet-Taft solvatochromic parameter scheme.About:
This article is published in Journal of Chromatography A.The article was published on 1993-12-17. It has received 130 citations till now.read more
Citations
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Quantitative structure-retention relationships applied to reversed-phase high-performance liquid chromatography
TL;DR: In this paper, a review of the theoretical background of QSRR and its application in the search for new reliable and precise descriptors of the structures of solutes of relevance to their properties, including properties other than chromatographic, e.g., bioactivity.
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Poisoning by plant material: review of human cases and analytical determination of main toxins by high-performance liquid chromatography-(tandem) mass spectrometry.
Yvan Gaillard,Gilbert Pépin +1 more
TL;DR: A general method for the detection of various toxins in whole blood by high-performance liquid chromatography coupled to mass spectromaetry or tandem mass spectrometry is developed and application to real forensic cases has been demonstrated.
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Trends and progress in the characterization of stationary phases for reversed-phase liquid chromatography
TL;DR: The state-of-the-art and progress in the characterization of reversed-phase liquid chromatographic (RPLC) columns are discussed in this paper, where existing column tests are compared with tests under development.
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Global linear solvation energy relationships for retention prediction in reversed-phase liquid chromatography
TL;DR: A global linear solvation energy relationship (LSER) that simultaneously models retention in reversed-phase liquid chromatography as a function of both solute LSER descriptors and mobile phase composition has been derived from both the local LSER model and the linear solvent strength theory (LSST) as discussed by the authors.
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Characterization of adsorption processes in analytical liquid-solid chromatography.
TL;DR: This review discusses nonlinear chromatographic methods of importance for proper characterization of the adsorption processes in analytical Chromatographic systems, with focus on reversed-phase liquid chromatography.
References
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Journal ArticleDOI
Linear solvation energy relationships. 23. A comprehensive collection of the solvatochromic parameters, .pi.*, .alpha., and .beta., and some methods for simplifying the generalized solvatochromic equation
TL;DR: In this article, a table of donnees (pour de nombreux solvants) des valeurs des parametres M*, α and β donnant respectivement la polarisabilite du solvant, son pouvoir de donneur de proton, and d'accepteur de protons dans les liaisons hydrogene solute-solvant
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Solvophobic interactions in liquid chromatography with nonpolar stationary phases
TL;DR: In this article, the solvophobic theory of solvent interaction with non-polar stationary phases in liquid chromatography is examined on the basis of solvophobia theory and a detailed analysis of the effect of the solvent on this process yields an expression for the capacity factor with essentially no adjustable constants.
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Classification of the solvent properties of common liquids
TL;DR: In this article, Rohrschneider's solubility data reported by 82 solvents and several test solutes have been transformed into a corresponding set of solvent characterization parameters: P ′, x c, x d and x n values.
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Optimization of solvent strength and selectivity for reversed-phase liquid chromatography using an interactive mixture-design statistical technique
TL;DR: In this article, a general scheme combines the Snyder solvent selectivity-triangle concept with a mixture-design statistical technique to optimize the strength and selectivity of mobile phase solvents for reversed-phase liquid chromatography (LC) separations.