Journal ArticleDOI
Spectral properties of mixed-ligand copper(II) complexes and their corresponding binary parent complexes
Reads0
Chats0
About:
This article is published in Inorganic Chemistry.The article was published on 1972-11-01. It has received 95 citations till now. The article focuses on the topics: Copper.read more
Citations
More filters
Journal ArticleDOI
Structural implications derived from the analysis of electron paramagnetic resonance spectra of natural and artificial copper proteins
TL;DR: It is concluded that in artificial copper proteins as well as in the naturally occurring nonblue copper proteins copper is ligated to oxygen and nitrogen but not to sulfur.
Journal ArticleDOI
Ternary Cu2+ Complexes: Stability, Structure, and Reactivity
TL;DR: In this article, the driving forces leading to the formation of ternary Cu2+ complexes are outlined; they are (i) statistical reasons, neutralization of charge in the mixed-ligand complexes, steric factors (bulky groups, ring size of chelates), and formation of π bonds.
Journal ArticleDOI
Oxidation by permanganate: synthetic and mechanistic aspects
TL;DR: In this article, alcohols and olefinic compounds undergo oxidation by permanganate through the formation of a substrate-Mn(VII) complex, which finally decomposes to give the desired products.
Book ChapterDOI
Active sites in copper proteins an electronic structure overview
TL;DR: In this paper, a detailed picture of the unique electronic structure of active sites in copper proteins is provided through a combination of complementary spectroscopic techniques, chemical perturbations, and parallel studies on copper complexes which serve as spectral analogues.
Journal ArticleDOI
Some factors influencing mixed complex formation
R. Bruce Martin,Ronald A. Prados +1 more
TL;DR: The tendency toward mixed complex formation may be expressed quantitatively in two different ways as mentioned in this paper : the most common approach is to compare the stability of the mixed complex with the two pure 2:1 complexes where two like ligands are bound to a single metal ion.
Related Papers (5)
Ternary complexes in solution. VIII. Complex formation between the copper(II)-2,2'-bipyridyl 1:1 complex and ligands containing oxygen and/or nitrogen donor atoms
Rolf Griesser,Helmut Sigel +1 more