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Spontaneously organized molecular assemblies. 4. Structural characterization of n-alkyl thiol monolayers on gold by optical ellipsometry, infrared spectroscopy, and electrochemistry

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This article is published in Journal of the American Chemical Society.The article was published on 1987-06-01. It has received 3009 citations till now. The article focuses on the topics: Alkyl & Infrared spectroscopy.

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Formation and Structure of Self-Assembled Monolayers.

Abraham Ulman
- 20 Jun 1996 - 
TL;DR: Monolayers of alkanethiolates on gold are probably the most studied SAMs to date and offer the needed design flexibility, both at the individual molecular and at the material levels, and offer a vehicle for investigation of specific interactions at interfaces, and of the effect of increasing molecular complexity on the structure and stability of two-dimensional assemblies.
Journal ArticleDOI

Synthesis of thiol-derivatised gold nanoparticles in a two-phase liquid-liquid system

TL;DR: Using two-phase reduction of AuCl4 by sodium borohydride in the presence of an alkanethiol, solutions of 1-3 nm gold particles bearing a surface coating of thiol have been prepared and characterised; this novel material can be handled as a simple chemical compound as mentioned in this paper.
Journal ArticleDOI

Structure and growth of self-assembling monolayers

TL;DR: In this article, the structural phases and the growth of self-assembled monolayers (SAMs) are reviewed from a surface science perspective, with emphasis on simple model systems, and a summary of the techniques used for the study of SAMs is given.
Journal ArticleDOI

Functionalized Monolayers on Ordered Mesoporous Supports

TL;DR: The surface modification scheme reported in this paper enables rational design of the surface properties of tailored porous materials and may lead to the synthesis of more sophisticated functionalized composites for environmental and industrial applications.
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