Journal ArticleDOI
Stereoselective Intramolecular Aminocarbonylation of 3-Hydroxypent-4-enylamides Catalyzed by Palladium
TLDR
The urethanes and to-samides of 3-hydroxypent-4-enylamine and its C1 C4 substituted derivatives undergo the palladium catalyzed intramolecular aminocarbonylation (0.1 equiv of PdCl2, 3.0 equivaliv of NaOAc in acetic acid under ca. 1 atm of CO).About:
This article is published in Tetrahedron Letters.The article was published on 1985-01-01. It has received 54 citations till now. The article focuses on the topics: Intramolecular reaction & Palladium.read more
Citations
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C-C, C-O, C-N bond formation on sp2 carbon by Pd(II)-catalyzed reactions involving oxidant agents.
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Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications
TL;DR: Enantioselective PdII-catalyzed functionalization of alkenes has experienced considerably less success than have many other classes of enantiOSElective transformations, despite the extensive history of the Wacker process and related oxidation reactions.
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Stereocontrolled cyclofunctionalizations of double bonds through heterocyclic intermediates
Giuliana Cardillo,Mario Orena +1 more
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Palladium-catalysed reactions of alcohols. Part B: Formation of C–C and C–N bonds from unsaturated alcohols
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Palladium‐Catalyzed Oxidative Carbonylation Reactions
TL;DR: The oxidative addition step could be potentially avoided in oxidative reactions, but only few reviews exist in this area, and the recent development in the oxidative carbonylation reactions are summarized.
References
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Journal ArticleDOI
Palladium-catalyzed cyclization of .omega.-olefinic tosamides. Synthesis of nonaromatic nitrogen heterocycles
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Intramolecular alkoxypalladation/carbonylation of alkenes
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Palladium-assisted cyclization-insertion reactions. Synthesis of functionalized heterocycles
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Palladium-catalyzed synthesis of pyrroles
TL;DR: Pyrrole derivatives are prepared in high yields by the catalytic action of a Pd(II) salt on 1-amino-3-alkyn-2-ols which are obtained from conjugate ynones.