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Journal ArticleDOI

Stereospecific total synthesis of (.+-.)-warburganal and related compounds

Steven P. Tanis, +1 more
- 01 Jul 1979 - 
- Vol. 101, Iss: 15, pp 4398-4400
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Synthesis of both the enantiomers of polygodial, an insect antifeedant sesouiterpene

TL;DR: Both the natural and unnatural enantiomers of polygodial, an insect antifeedant sesquiterpene of the drimane family, were synthesized starting from (S) -3- hydroxy-2,2-dimethylcyclohexanone as a single chiral source as mentioned in this paper.
Journal ArticleDOI

One-pot conversion of primary alcohols to α-oxygenated alkanals with TEMPO in combination with molecular oxygen and ruthenium complex

TL;DR: In this paper, the reaction of primary alcohols with an oxidizing system composed of 4-BzO'TEMPO (2 equiv.), RuCl 2 (PPh 3 ) 3 as a catalyst, and molecular oxygen leads to concomitant oxidation and substitution, giving the corresponding α-oxygenated alkanals.
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