Journal ArticleDOI
Stickstoffreiche energetische Salze und ionische Flüssigkeiten
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TLDR
In this paper, die Verwendung von stickstoffhaltigen Kationen und Anionen tragt zu hoheren Bildungswarmen und Dichten bei, wobei durch den niedrigen Gehalt an Kohlenstoff und Wasserstoff auch eine gute Sauerstoffbilanz erzielt wird.Abstract:
Energetische Salze bieten zahlreiche Vorteile gegenuber herkommlichen energetischen Molekulverbindungen. Die Verwendung von stickstoffhaltigen Kationen und Anionen tragt zu hoheren Bildungswarmen und Dichten bei, wobei durch den niedrigen Gehalt an Kohlenstoff und Wasserstoff auch eine gute Sauerstoffbilanz erzielt wird. Da bei der Zersetzung dieser stickstoffreichen Verbindungen ein groserer Anteil von Distickstoff entsteht, sind sie vielversprechende hochenergetische Materialien fur technische und militarische Anwendungen.read more
Citations
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Journal ArticleDOI
Green Pyrotechnics : A Chemists' Challenge
TL;DR: This Review summarizes the sources of pollution in current formulations and recent efforts toward "green" pyrotechnics.
Journal ArticleDOI
Synthesis and promising properties of a new family of high-density energetic salts of 5-nitro-3-trinitromethyl-1H-1,2,4-triazole and 5,5'-bis(trinitromethyl)-3,3'-azo-1H-1,2,4-triazole.
TL;DR: High density, moderate to good thermal stability, acceptable oxygen balance, reasonable heat of formation, and excellent detonation properties, which in some cases are superior to those of 1,3,5,5,-trinitrotriazacyclohexane (RDX).
Journal ArticleDOI
The CN7(-) anion.
TL;DR: Several salts containing the CN7(-) anion were prepared by deprotonation of 5-azido-1H-tetrazole by characterized by low temperature single X-ray diffraction, resulting in values which belong to primary explosives.
Journal ArticleDOI
Ionic Liquids as Hypergolic Fuels
TL;DR: A new family of dicyanoborates is presented, which can be synthesized in water, with substituted N-acyclic, N-cyclic, and azolium cations has met nearly all of the desired important criteria needed for well-performing fuels.
Journal ArticleDOI
High‐Density Energetic Mono‐ or Bis(Oxy)‐5‐Nitroiminotetrazoles
TL;DR: The aim of this study was to elucidate the structures in the crystalline state using X-ray diffraction analysis and to find new, potent oxygenand nitrogen-rich tetrazoles, with potentially significant physical and energetic properties.
References
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Journal ArticleDOI
Ionic Liquids-New "Solutions" for Transition Metal Catalysis.
Peter Wasserscheid,Wilhelm Keim +1 more
TL;DR: There are indications that switching from a normal organic solvent to an ionic liquid can lead to novel and unusual chemical reactivity, which opens up a wide field for future investigations into this new class of solvents in catalytic applications.
Book
Ionic Liquids in Synthesis
Peter Wasserscheid,Tom Welton +1 more
TL;DR: The early years of Ionic liquid production were covered in this article, where a new generation of soluble supports for Supported Organic Synthesis (SPOS) was proposed. But this support was not applied to the task-specific Ionic liquids.
Journal ArticleDOI
Chemical and biochemical transformations in ionic liquids
TL;DR: The synthesis of ionic liquids and their applications in various chemical and biochemical transformations, in ecofriendly-milder conditions have been reviewed in this paper, with metal and enzyme catalyzed as well as non-catalyzed reactions in ionic liquid reactions covered with 354 refs.
MonographDOI
Ionic liquids as green solvents : progress and prospects
TL;DR: Following Ionic Liquids: Industrial Applications to Green Chemistry, SS #818, by the same editors, the authors focuses on exciting new developments in ionic liquids and focuses on the application of ionic solvents in green chemistry.