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Structural and functional evolution of metallacrowns.
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This article is published in Chemical Reviews.The article was published on 2007-11-14. It has received 435 citations till now. The article focuses on the topics: Metallacrown.read more
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Supramolecular coordination chemistry: the synergistic effect of serendipity and rational design.
TL;DR: This Review emphasizes the achievements in supramolecular coordination chemistry initiated by serendipity and their materialization based on rational design and the design of rational strategies for the construction of a variety of nanosized systems with specified size and shape.
Journal ArticleDOI
Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes
Ke Liu,Wei Shi,Peng Cheng +2 more
TL;DR: In this paper, a review of 3d-4f heterometallic discrete complexes is presented, focusing on the examples showing dynamics of the magnetization, as well as the synthetic strategy, structures and magnetic properties.
Journal ArticleDOI
Uncommon lanthanide ions in purely 4f Single Molecule Magnets
TL;DR: The use of lanthanide ions in the design of SMMs exploded with the discovery of the first example of mononuclear TbIII-based complex which displayed a slow magnetic relaxation in 2003 as discussed by the authors.
Journal ArticleDOI
Self-assembled coordination complexes from various palladium(II) components and bidentate or polydentate ligands
TL;DR: In this article, the authors describe self-assemblies formed by the combination of a variety of palladium(II) components and ligands ranging from bi-to polydentate.
Journal ArticleDOI
Assembly of Near‐Infrared Luminescent Lanthanide Host(Host–Guest) Complexes With a Metallacrown Sandwich Motif
Joseph Jankolovits,Christopher M. Andolina,Jeffrey W. Kampf,Kenneth N. Raymond,Kenneth N. Raymond,Vincent L. Pecoraro +5 more
TL;DR: A self-assembly approach to realizing long-lived Ln luminescence in the NIR region is presented by utilizing the unique metallacrown (MC) topology to eliminate high energy X H oscillators from within 6.7 of the lanthanide ion.
References
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Journal ArticleDOI
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
TL;DR: The effective ionic radii of Shannon & Prewitt [Acta Cryst. (1969), B25, 925-945] are revised to include more unusual oxidation states and coordinations as mentioned in this paper.
MonographDOI
Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
Journal ArticleDOI
Magnetic bistability in a metal-ion cluster
TL;DR: In this article, it was shown that the magnetization of the Mn12 cluster is highly anisotropic and the magnetisation relaxation time becomes very long below a temperature of 4 K, giving rise to pronounced hysteresis.
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Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals
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Supramolecular Chemistry—Scope and Perspectives Molecules, Supermolecules, and Molecular Devices (Nobel Lecture)
TL;DR: Developments in molecular and supramolecular design and engineering open perspectives towards the realization of molecular photonic, electronic, and ionic devices that would perform highly selective recognition, reaction, and transfer operations for signal and information processing at the molecular level.