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Structure and redox properties of the water-oxidation catalyst [(bpy)2(OH2)RuORu(OH2)(bpy)2]4+

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This article is published in Journal of the American Chemical Society.The article was published on 1985-01-01. It has received 439 citations till now. The article focuses on the topics: Redox & Catalysis.

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Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds

TL;DR: The Scope of Review: Large-Scale Centralized Energy Storage, Chemical Energy Storage: Solar Fuels, and Capacitors 6486 5.1.2.
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Proton-Coupled Electron Transfer

TL;DR: Proton-coupled electron transfer is an important mechanism for charge transfer in a wide variety of systems including biology- and materials-oriented venues and several are reviewed.
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The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis

TL;DR: In this article, a review compares and unifies viewpoints on water oxidation from various fields of catalysis research, including thermodynamic efficiency and mechanisms of electrochemical water splitting by metal oxides on electrode surfaces, explaining the recent concept of the potential determining step.
Journal ArticleDOI

Chemical approaches to artificial photosynthesis

TL;DR: In this article, a modular assembly approach is proposed to integrate light absorption, energy transfer, and long-range electron transfer by use of free-energy gradients into single molecular assemblies or on separate electrodes in photelectrochemical cells.
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Earth-Abundant Heterogeneous Water Oxidation Catalysts

TL;DR: It is suggested that future advances in solar fuels science will be accelerated by the development of new methods for materials synthesis and characterization, along with in-depth investigations of redox mechanisms at catalytic surfaces.
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