Journal ArticleDOI
Structure of tris(bis(trimethylsilyl)amido)neodymium(III), Nd[N(Si(CH3)3)2]3
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This article is published in Inorganic Chemistry.The article was published on 1978-03-01. It has received 119 citations till now. The article focuses on the topics: Trimethylsilyl.read more
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Book ChapterDOI
Neodymium-Based Ziegler/Natta Catalysts and their Application in Diene Polymerization
TL;DR: In this paper, a review of the polymerization of dienes by neodymium-based Ziegler/Natta-catalyst systems is presented, focusing on the monomer 1,3-butadiene (BD).
Journal ArticleDOI
Bimetallic carbonyl thiolates as functional models for Fe-only hydrogenases.
TL;DR: Electrochemical and analytical data show that reduction of 2H(2)(+) gives H(2) and 2(-), and DFT calculations establish that the regiochemistry of protonation is subtly dependent on the coligands but is more favorable to occur at the Fe-Fe bond.
Journal ArticleDOI
Structural criteria for the mode of bonding of organoactinides and -lanthanides and related compounds
TL;DR: In this paper, the authors summarized much of the structural information accumulated during the last ten years, focusing on the unifying structural trends in these compounds and the question of the mode of bonding.
Book ChapterDOI
Agostic Interactions from a Computational Perspective: One Name, Many Interpretations
Eric Clot,Odile Eisenstein +1 more
TL;DR: The agostic bond defines an intramolecular interaction where a σ bond is geometrically close to an electron deficient center (often a transition metal).
Journal ArticleDOI
A Trigonal‐Pyramidal Erbium(III) Single‐Molecule Magnet
TL;DR: A new SMM is reported, [Li(THF)4[Er{N(SiMe3)2}3Cl]⋅2 THF, which exhibits slow relaxation of the magnetization under zero dc field with an effective barrier to the reversal of magnetization.