Journal ArticleDOI
Structures of alkali and alkaline earth metal clusters with oxygen donor ligands
TLDR
In this paper, a review based on 169 references gives an actual overview on group 1 and 2 clusters with oxygen donor ligands, starting with Mg-compounds, then pursuing with the heavier homologues.About:
This article is published in Polyhedron.The article was published on 2004-05-27. It has received 66 citations till now. The article focuses on the topics: Alkali metal.read more
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Coordination polymer networks with s-block metal ions
TL;DR: In this paper, a review of the recent results in the field of metal-organic frameworks (MOFs) is presented, bringing together the systematic approaches with results obtained by serendipity to give an overview on current and future possibilities.
Journal ArticleDOI
Structure formation principles and reactivity of organolithium compounds.
TL;DR: An overview over the structural principles of lithium organics and their Lewis base coordinated complexes in the solid state is given and the structure-reactivity relationship is depicted by means of the reactivity of the Lewis bases towards intramolecular decomposition reactions with the organolithium compound.
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Recent developments in the field of organic heterobimetallic compounds of the alkaline-earth metals.
TL;DR: Heterobimetallic compounds of the alkaline-earth metals show a wide structural variety with strongly differing reactivity patterns and electronegative substituents at tin an inverse coordination mode such as M[(mu-R)(2)SnR](2) is observed.
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Structural diversity and supramolecular aggregation in calcium, strontium, and barium salicylates incorporating 1,10-phenanthroline and 4,4'-bipyridine: probing the softer side of group 2 metal ions with pyridinic ligands.
Ramaswamy Murugavel,Remya Korah +1 more
TL;DR: The results obtained for the calcium complexes in this study have been compared with the available data in structural calcium chemistry with the aid of a detailed analysis of the Cambridge Structural Database.
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50 years of superbases made from organolithium compounds and heavier alkali metal alkoxides
Lubomír Lochmann,Miroslav Janata +1 more
TL;DR: A review of reactions of organolithium compounds (RLi) with alkali metal alkoxides is presented in this paper, where an improved mechanism of metal interchange and reaction of superbases with substrates is proposed.
References
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Journal ArticleDOI
Hard and soft acids and bases
TL;DR: In this paper, the rate data for the generalized nucleophilic displacement reaction were reviewed, and the authors presented a method to estimate the rate of the generalized displacement reaction in terms of the number of nucleophiles.
Journal ArticleDOI
Superconductivity at 94 K in HgBa 2 Cu0 4+δ
TL;DR: In this article, the same authors reported the synthesis of the related compound HgBa2CuO4+δ (Hg-1201), with only one CuO2 layer per unit cell, and showed that it is superconducting below 94 K.
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Structure and Reactivity of Lithium Enolates. From Pinacolone to Selective C‐Alkylations of Peptides. Difficulties and Opportunities Afforded by Complex Structures
TL;DR: The chemistry of lithium enolates is used to demonstrate that complex structures held together by noncovalent bonds (supramolecules) may dramatically influence the result of seemingly simple standard reactions of organic synthesis as mentioned in this paper.