Journal ArticleDOI
Structuring of the solvent at metal/solution interfaces and components of the electrode potential*
TLDR
In this paper, it is shown that σXM is probably overestimated in calculations, but it cannot be neglected, and that all discussions neglecting it should retain their qualitative validity.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1983-07-25. It has received 71 citations till now. The article focuses on the topics: Surface roughness & Work function.read more
Citations
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Coverage‐dependent dipole coupling for carbon monoxide adsorbed at ordered platinum(111)‐aqueous interfaces: Structural and electrochemical implications
Si-Chung Chang,Michael J. Weaver +1 more
TL;DR: In this article, surface infrared spectra in the terminal C-O stretching region are reported for various 12CO/13CO mixtures adsorbed on an ordered Pt(111) electrode in 0.1 M HClO4 as a function of CO coverage.
Journal ArticleDOI
The potential of zero total charge of Pt nanoparticles and polycrystalline electrodes with different surface structure The role of anion adsorption in fundamental electrocatalysis
TL;DR: In this paper, the potentials of zero total charge (pztc) were determined by using the CO displacement approach, both in sulphuric and perchloric media.
Journal ArticleDOI
Structure of the metal/electrolyte solution interface: new data for theory
TL;DR: In this paper, the relationship between electrode potential and work function measurements has been investigated, and new data have been scrutinized with the purpose of offering new suggestions and new fundamental arguments for the theoretical modelling of the electrical double layer.
Journal ArticleDOI
Dependence of the Potential of Zero Charge of Stepped Platinum (111) Electrodes on the Oriented Step-Edge Density: Electrochemical Implications and Comparison with Work Function Behavior
TL;DR: In this paper, the dependence of the potential of zero charge (pzc) for Pt(111) surfaces in acidic aqueous solution having increasing densities of ordered monoatomic steps in the (111)−(110) and (111)-−(100) zones is evaluated from CO "charge-displacement" measurements, with the objective of elucidating the influence of the electrochemical double layer on the large step-induced changes in surface potential known for the clean uncharged surfaces in ultrahigh vacuum (UHV).
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The structure of water at a Pt(111) electrode and the potential of zero charge studied from first principles
TL;DR: The reliability of the chosen exchange-correlation function has been validated by considering water clusters, bulk ice structures, and bulk liquid water, confirming that the dispersion corrected RPBE-D3/zero functional is a suitable choice for first-principles calculations addressing electrochemical aqueous electrolyte/metal electrode interfaces.
References
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Book
Modern Aspects of Electrochemistry
TL;DR: In this paper, the authors focus on topics at the forefront of electrochemical research, such as splitting water by electrolysis, splitting water with visible light, and the recent development of lithium batteries.
Journal ArticleDOI
Advances in Electrochemistry and Electrochemical Engineering
P. Delahay,Ashok K. Vijh +1 more
Journal ArticleDOI
Anisotropy of the Electronic Work Function of Metals
TL;DR: In this paper, the authors used the picture of Wigner and Bardeen according to which the work function is a sum of a volume contribution and a contribution due to a double layer on the surface of the metal.