Journal ArticleDOI
Study of half-sandwich platinum group metal complexes bearing dpt-NH2 ligand
TLDR
In this paper, a general approach for the preparation of η5 and η6-cyclichydrocarbon platinum group metal complexes is reported, and the molecular structures of 4 and 6 have been established by single crystal X-ray diffraction and some of the representative complexes have also been studied by UV-Vis spectroscopy.About:
This article is published in Polyhedron.The article was published on 2010-02-01. It has received 17 citations till now. The article focuses on the topics: Ruthenium & Cyclopentadienyl complex.read more
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Journal ArticleDOI
Half-sandwich arene ruthenium complexes: synthetic strategies and relevance in catalysis
TL;DR: Half-sandwich arene ruthenium complexes exhibit versatile chemistry, serve as excellent precursors and find potential applications in many organic transformations and their applications in catalytic organic transformations are discussed.
Journal ArticleDOI
Application of arene ruthenium(II) complexes with pyridine-2-carboxaldimine ligands in the transfer hydrogenation of ketones
TL;DR: The reaction of various pyridine-2-carboxaldimine ligands with the [(η6-arene)RuCl(C5H4N-2 CH N-Ar]PF6]2 dimer followed by a metathesis reaction with ammonium hexaflourophosphate, yielded the ruthenium(II) arene complex salts, which were suitable for a wide range of aliphatic, cyclic and aromatic ketones giving good turn over numbers.
Journal ArticleDOI
Enantioselective transfer hydrogenation of ketone catalysed by artificial metalloenzymes derived from bovine β-lactoglobulin
TL;DR: Artificial metalloproteins resulting from the embedding of half-sandwich Ru(II)/Rh(III) fatty acid derivatives within β-lactoglobulin catalysed the asymmetric transfer hydrogenation of trifluoroacetophenone with modest to good conversions and fair ee's.
Journal ArticleDOI
Half-sandwich ruthenium(II) complexes with N- and N,(N,O)-donor ligands: molecular, electronic structures, and computational study
TL;DR: In this paper, four η6p-cymene ruthenium(II) complexes with 2-(2-aminophenyl)-1H-benzimidazole (BImPhNH), 2-aminobenzimidaze (BimNH), 1H-Benzoxazole(HBO) and 2-hydroxyphenyl (HBO)-benzoxaze (HB) ligands have been prepared and studied by IR, NMR, UV-Vis spectroscopy, and X-ray crystallography
Journal ArticleDOI
Study of new mononuclear platinum group metal complexes containing η5 and η6 – Carbocyclic ligands and nitrogen based derivatives and formation of helices due to NH⋯Cl interactions
TL;DR: A quite general approach for the preparation of η 5 and η 6 -cyclichydrocarbon platinum group metal complexes is reported in this paper, where the dinuclear arene ruthenium complexes are obtained in the presence of two equivalents of the ligands 2-chloro-3-(pyrazolyl)quinoxaline (L 1 ) and di-(2-pyridyl)amine (L 2 ) to afford the corresponding mononuclear complexes.
References
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ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI)
TL;DR: L Lists of software presented and~or reviewed in the Journal of Applied Crystallography are available on the World Wide Web at the above address, together with information about the availability of the software where this is known.
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Phase annealing in SHELX-90: direct methods for larger structures
TL;DR: In this article, a phase annealing method, related to the simulated-annealing approach in other optimization problems, is proposed and it is shown that it can result in an improvement of up to an order of magnitude in the chances of solving large structures at atomic resolution.
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Mixed phosphine 2,2'-bipyridine complexes of ruthenium
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Arene ruthenium(II) complexes formed by dehydrogenation of cyclohexadienes with ruthenium(III) trichloride
TL;DR: In this article, the same authors compared their results with available data on arene exchange in arenetricarbonylchromium complexes and discussed in terms of electronic and steric effects on metal-arene bonding.