Journal ArticleDOI
Study of the hydrogen bond donor acidity of binary aqueous mixtures and their role in reversed-phase liquid chromatography
TLDR
In this article, the solvatochromic hydrogen bond donor acidity parameter (αmix) of aqueous mixtures of methanol, acetonitrile, propan-2-ol and tetrahydrofuran were determined spectrophotometrically.About:
This article is published in Journal of Physical Organic Chemistry.The article was published on 1994-12-01. It has received 28 citations till now. The article focuses on the topics: Reversed-phase chromatography & Tetrahydrofuran.read more
Citations
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Journal ArticleDOI
Fundamental challenges and opportunities for preparative supercritical fluid chromatography.
TL;DR: A clearer understanding of the physico-chemical behavior of supercritical fluids in preparative chromatographic columns under nonlinear conditions is still needed, which seems to be the main obstacle to the establishment of SFC as a sustainable separation tool.
Journal ArticleDOI
Study of retention in reversed-phase liquid chromatography using linear solvation energy relationships
Lay Choo Tan,Peter W. Carr +1 more
Journal ArticleDOI
Structural changes in W/O triton X-100/cyclohexane-hexanol/water microemulsions probed by a fluorescent drug Piroxicam
TL;DR: In this article, the photophysics of a fluorescent drug Piroxicam was used to probe the intramicellar region of nonionic microemulsions of Triton X-100/cyclohexane/water, using both steady-state and transient (picosecond resolution) techniques.
Journal ArticleDOI
Solvatochromism in pure and binary solvent mixtures: effects of the molecular structure of the zwitterionic probe
TL;DR: In this article, the solvatochromic behavior of 2,6-dichloro-4-(2,4-6-triphenyl-1-pyridinio)phenolate (WB) was studied by UV-visible spectrophotometry in 32 pure solvents, in binary mixtures of 1-butanol-cyclohexane (BuOH-Cyhx), and of water with methanol, ethanol, 1-propanol, 2-butoxyethanol (2-BE), acetonitrile
Journal ArticleDOI
Characterization of some normal-phase liquid chromatographic stationary phases based on linear solvation energy relationships
TL;DR: In this article, a number of normal-phase liquid chromatography (NP-LC) stationary phases were characterized by estimating characteristic interaction constants for the stationary phases based on linear solvation energy relationships.
References
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Journal ArticleDOI
Local compositions in thermodynamic excess functions for liquid mixtures
Henri Renon,John M. Prausnitz +1 more
TL;DR: In this paper, a new equation based on Scott's two-liquid model and on an assumption of nonrandomness similar to that used by Wilson is derived, which gives an excellent representation of many types of liquid mixtures.
Journal ArticleDOI
Statistical thermodynamics of liquid mixtures: A new expression for the excess Gibbs energy of partly or completely miscible systems
D. S. Abrams,John M. Prausnitz +1 more
TL;DR: The UNIQUAC equation as discussed by the authors is a semi-theoretical equation for the excess Gibbs energy of a liquid mixture, which is generalized through introduction of the local area fraction as the primary concentration variable.
Journal ArticleDOI
Distribution phenomena of mobile-phase components and determination of dead volume in reversed-phase liquid chromatography
R. M. McCormick,Barry L. Karger +1 more
Journal ArticleDOI
Study of retention processes in reversed-phase high-performance liquid chromatography by the use of the solvatochromic comparison method.
Paul C. Sadek,Peter W. Carr,Ruth M. Doherty,Mortimer J. Kamlet,R. W. Taft,Michael H. Abraham +5 more
Journal ArticleDOI
Solute–solute interactions in water. II. An analysis through the Kirkwood–Buff integrals for 14 organic solutes
E. Matteoli,Luciano Lepori +1 more
TL;DR: In this paper, the Kirkwood-Buff integrals Gij defined by Gij =∫∞0 [gij(r) −1] 4πr2dr=f(a,V,K), (i=1,2; j= 1,2), have been calculated in the whole concentration range.
Related Papers (5)
The solvatochromic comparison method. I. The .beta.-scale of solvent hydrogen-bond acceptor (HBA) basicities
Mortimer J. Kamlet,R. W. Taft +1 more
The use of characteristic volumes to measure cavity terms in reversed phase liquid chromatography
Michael H. Abraham,J. C. McGowan +1 more