Journal ArticleDOI
Supporting conformational change at metal centres. Part 2: four and five coordinate geometry
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In this paper, the X-ray crystal structures of pyridino-(N,N′-bis(salicylidene)-1,2-ethylenediamine) zinc are reported.About:
This article is published in Polyhedron.The article was published on 2002-09-15. It has received 102 citations till now. The article focuses on the topics: Zinc.read more
Citations
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Supramolecular Assembly of Zinc Salphen Complexes: Access to Metal‐Containing Gels and Nanofibers
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Zinc-centred salen complexes: versatile and accessible supramolecular building motifs.
TL;DR: This Frontier reviews the recent applications of these molecular building blocks in supramolecular chemistry, and their potential in various fields of material science.
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Supramolecular Assembly and Coordination‐Assisted Deaggregation of Multimetallic Macrocycles
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Molecular design of mononuclear complexes of acyclic Schiff-base ligands
TL;DR: In this paper, the fine structure of Schiff-base ligand systems (metallocycle sizes and their number, nature of donor centers, aldehyde and amine fragments, co-ligands) are examined.
References
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Crystal and molecular structure of and magnetic coupling in two complexes containing gadolinium(III) and copper(II) ions
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Quadridentate and Sexadentate Chelates. Some Preliminary Studies in their Preparation and Thermal Stability1
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Supporting conformational change at metal centres. Part 1: octahedral systems
TL;DR: In this article, the X-ray crystal structures of N,N′-bis(salicylidene)-1,2-ethylenediamine and 1,3-propanediamine seem to be constrained by the chelate ring generated by the imine groups.
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Spectrophotometric study of the equilibria between nickel(ii) schiff-base complexes and alkaline earth or nickel(ii) cations in acetonitrile solution
TL;DR: Examination of adduct formation between M(ClO(4) and nickel(II) complexes of tetradentate Schiff-base ligands in acetonitrile found that the nickel atom, coordinated to two [Ni(salen)] complexes, has a distorted octahedral geometry and completes its coordination by linking two molecules of water.
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Studies in the stereochemistry of zinc(II). VI. Zinc complexes with quadridentate Schiff bases
GE Batley,DP Graddon +1 more
TL;DR: In this paper, it was shown that anhydrous zinc complexes with 2-3 carbon chains readily form 1 : 1 adducts with water or bases such as pyridine, the zinc being 5-coordinate.