Journal ArticleDOI
Suppression of unwanted heterogeneous platinum(0)-catalyzed reactions by poisoning with mercury(0) in systems involving competing homogeneous reactions of soluble organoplatinum compounds: thermal decomposition of bis(triethylphosphine)-3,3,4,4-tetramethylplatinacyclopentane
George M. Whitesides,Marifaith. Hackett,Robert L. Brainard,Jean Paul P. M. Lavalleye,Alan F. Sowinski,Alan N. Izumi,Stephen S. Moore,Duncan W. Brown,Erin M. Staudt +8 more
TLDR
In this paper, a simple preparation of 1,4-dihalo-2,2,3,3-tetramethylbutane and l-methyl-l-tert:butylcyclopropane is presented.About:
This article is published in Organometallics.The article was published on 1985-10-01. It has received 309 citations till now. The article focuses on the topics: Organoplatinum & Catalysis.read more
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On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
TL;DR: A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki coupling reactions over the last 15 years as mentioned in this paper, and there are now many suggestions in the literature that narrow the scope of types of precatalyst that may be considered true catalysts in these coupling reactions.
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Reduced transition metal colloids: a novel family of reusable catalysts
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A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions
TL;DR: In this article, the authors consider cases in which a discrete transition-metal complex is used as a precatalyst for reductive catalysis and focus on the problem of determining if the true catalyst is a metal-complex homogeneous catalyst or if it is a soluble or other metal-particle heterogeneous catalyst.
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Transition Metal Nanocluster Formation Kinetic and Mechanistic Studies. A New Mechanism When Hydrogen Is the Reductant: Slow, Continuous Nucleation and Fast Autocatalytic Surface Growth
TL;DR: In this article, the P2W15Nb3O629 polyoxoanion and Bu4N+- stabilized Ir∼190-450 (hereafter, Ir(0)∼300) nanoclusters are presented.
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Recyclable Heterogeneous Palladium Catalysts in Pure Water: Sustainable Developments in Suzuki, Heck, Sonogashira and Tsuji–Trost Reactions
TL;DR: In this paper, a review summarizes the progress made essentially these last ten years on heterogeneous palladium catalysis in pure water and discusses the efficiency and reusability of the heterogeneous catalysts as well as the experimental conditions from a sustainable chemistry point of view.
References
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Reagents for Organic Synthesis
TL;DR: In this paper, the authors propose a method for using Reference Abbreviations (RABs) as a reference abbreviation for reference abbreviations in the context of bioinformatics.