Journal ArticleDOI
Syntheses and Characterization of Coordination Compounds of 3d-Metal 5-Sulfosalicylates with Phenylacethydrazide: Crystal Structure of [Ni(L)3]HSSal · 3H2O (L is Phenylacethydrazide, and HSSal2– is 5-Sulfosalicylic Acid Anion)
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TLDR
In this paper, a 3d-metal 5-sulfosalicylates with phenylacethydrazide is synthesized, and the complex is characterized by the methods of chemical analysis, IR spectroscopy, diffuse reflectance spectrography, luminescence, and thermogravimetry.Abstract:
The complexes of 3d-metal 5-sulfosalicylates with phenylacethydrazide are synthesized: [Co(L)3]HSSal · 3H2O (I), [Ni(L)3]HSSal · 3H2O (II), and [Zn(L)3]HSSal · 6H2O (III) (L is phenylacethydrazide, and HSSal2– is 5-sulfosalicylic acid anion). Compounds I–III are characterized by the methods of chemical analysis, IR spectroscopy, diffuse reflectance spectroscopy, luminescence, and thermogravimetry. Compound II is studied by X-ray diffraction analysis (СIF file CCDC no. 1819696). In the complex cation [Ni(L)3]2+, the nickel atom has a face octahedral coordination mode by three O atoms and three N atoms of three bidentate chelate ligands L. The complex cations, HSSal2– anions, and crystallization water molecules are joined by a branched system of hydrogen bonds. Complexes I–III are luminescent, and complex III exhibits the brightest luminescence.read more
Citations
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Journal ArticleDOI
5-Sulfosalicylato Cu(II), Zn(II) and Ni(II) coordination compounds with benzohydrazide: Synthesis, structure and luminescent properties
TL;DR: In this paper , three new 5-sulfosalicylato 3 d -metal coordination compounds with benzohydrazide have been synthesized and studied by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction.
Journal ArticleDOI
Synthesis, Crystal Structure, and Molecular Structure of Maleate Tris(Benzohydrazide) Cobalt(II) Tetrahydrate [Co(L1)3](Mal) · 4H2O and Maleate Tris(Phenylacethydrazide) Nikel(II) Monohydrate [Ni(L2)3](Mal) · H2O
V. S. Sergienko,V. S. Sergienko,T. V. Koksharova,M. D. Surazhskaya,T. V. Mandzii,Andrei V. Churakov +5 more
TL;DR: Coordination compounds [Co(L1)3]-Mal · 4H2O (I) and [Ni(L2)3])Mal · H2O(II) (L1 is benzohydrazide, L2 is phenylacethydrazide and H2Mal is maleic acid) have been synthesized and characterized by IR spectroscopy and diffuse reflectance spectrography as discussed by the authors.
Journal ArticleDOI
Synthesis and Characterization of Coordination Compounds of 3 d -Metal Malonates with Phenylacetyl Hydrazide. Crystal Structure of [Cu(L) 2 ][Cu(Mal) 2 ] · 4.5H 2 O (L Is Phenylacetyl Hydrazide, Mal 2– Is Malonic Acid Anion)
TL;DR: In this paper, three phenylacetyl hydrazide malonate complexes [M(L3)](Mal) of cobalt(II), nickel(II) (II), and zinc(II, III), as well as complex [Cu(L)2][Cu(Mal)/4.5H2O (IV) are synthesized.
References
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A short history of SHELX
TL;DR: This paper could serve as a general literature citation when one or more of the open-source SH ELX programs (and the Bruker AXS version SHELXTL) are employed in the course of a crystal-structure determination.
Journal ArticleDOI
Completion and refinement of crystal structures with SIR92
TL;DR: In this paper, an automatic procedure for recovering a complete crystal structure after a direct phasing process is described, which consists mainly of a Fourier recycling method that can be implemented in any direct-methods package.
Book
The Chemist's Companion: A Handbook of Practical Data, Techniques, and References
Arnold J. Gordon,Richard A. Ford +1 more
TL;DR: In this paper, the authors present a survey of the properties of molecular systems and their applications in the field of chemistry, including the following: properties of the elements, properties of molecules, and properties of compounds.