BookDOI
Synthesis and Application of Organoboron Compounds
Elena Fernández,Andrew Whiting +1 more
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TLDR
In this paper, the Suzuki-Miyaura cross-coupling of borocations has been used for boron-containing polymers, including alkenyl/ alkyl and allylboron compounds.Abstract:
Boryl anions.- Fundamental and applied properties of borocations.- Asymmetric catalytic borylation reactions.- Metal-catalyzed annulation of alkynylboronates.- Improving transformation through organotrifluoroborates.- Principles on dehydrocoupling of phosphine-boranes and amine-boranes Stereoselective Suzuki-Miyaura cross-coupling including alkenyl / alkyl and allylboron compounds.- Boronic acid catalysed reactions.- Stereospecific coupling throughout Lithiation/Borylation.- Boron-containing polymers.read more
Citations
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Journal ArticleDOI
Stereospecific functionalizations and transformations of secondary and tertiary boronic esters
TL;DR: This feature article summarises the current state of the art in stereospecific transformations of both secondary and tertiary boronic esters into other functionalities and groups, whilst considering critically the transformations that are currently unattainable and would represent future advances to the field.
Journal ArticleDOI
Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds.
TL;DR: This Review provides an overview of the latest methods for the controlled synthesis of B-B single and multiple bonds as well as the ever-expanding range of reactivity displayed by B- B multiple bonds.
Journal ArticleDOI
Boronic acid catalysis
TL;DR: The ability of boronic acids to form reversible covalent bonds with hydroxy groups can be exploited to enable both electrophilic and nucleophilic modes of activation in various organic reactions, leading to mild and selective reaction conditions that display high atom-economy.
Journal ArticleDOI
Merging Photoredox with 1,2-Metallate Rearrangements: The Photochemical Alkylation of Vinyl Boronate Complexes
TL;DR: Vinyl boronates react with electron-deficient alkyl iodides in the presence of visible light to give boronic esters in which two new C-C bonds have been created.
Journal ArticleDOI
Cobalt-Catalyzed Asymmetric Hydroboration/Cyclization of 1,6-Enynes with Pinacolborane
TL;DR: A cobalt-catalyzed asymmetric hydroboration/cyclization of 1,6-enynes with catalysts generated from Co(acac)2 and chiral bisphosphine ligands and activated in situ by reaction with pinacolborane (HBpin).
References
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Book ChapterDOI
The Catalytic Dehydrocoupling of Amine–Boranes and Phosphine–Boranes
TL;DR: In this article, the authors present a review of the mechanistic landscape for the dehydrocoupling of phosphine-boranes and amine-naphroxymethylene.
Book ChapterDOI
At the Forefront of the Suzuki–Miyaura Reaction: Advances in Stereoselective Cross-Couplings
Ho-Yan Sun,Dennis G. Hall +1 more
TL;DR: The latest achievements in the development of stereoselective Suzuki–Miyaura cross-coupling reactions are described, including advances made both in atroposelectives couplings as well as stereoselectedive C(sp3) couplings.
Related Papers (5)
Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more