Journal ArticleDOI
Synthesis and characterization of a molecularly imprinted silica gel sorbent for the on-line determination of trace sudan I in chilli powder through high-performance liquid chromatography
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TLDR
The results showed that the imprinted sorbent exhibited good recognition and selective ability, offered a faster kinetics for the adsorption and desorption of Sudan I than the non-imprinted sorbent, and had a saturated binding capacity (Qmax) that reached 33.47 mg g-1.Abstract:
A highly selective imprinted polymer was synthesized by a surface molecular imprinting technique in combination with a sol−gel process. The imprinted polymer was evaluated by FT-IR and static and kinetic adsorption experiments. The results showed that the imprinted sorbent exhibited good recognition and selective ability, offered a faster kinetics for the adsorption and desorption of Sudan I than the non-imprinted sorbent, a saturated binding capacity (Qmax) that reached 33.47 mg g-1. The prepared sorbent was applied for the determination of trace Sudan I through on-line solid-phase coupled with high-performance liquid chromatography (SPE-HPLC). With a loading flow rate of 1.5 mL min-1 for sampling 50 mL, an enrichment factor of 1266 was achieved. The detection limit (S/N = 3) was 1.2 ng L-1, and the peak area precision (RSD) for five replicate detections of 0.01 μg L-1 Sudan I was 3.66%. The Sudan I in the chilli powder from the local market was determined at three levels (0.25, 0.5, and 1.0 ng g-1) with...read more
Citations
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Journal ArticleDOI
Molecular imprinting science and technology: a survey of the literature for the years 2004-2011.
TL;DR: A survey of the literature covering the development of molecular imprinting science and technology over the years 2004–2011 and efforts to apply these polymeric materials to a range of application areas is presented.
Journal ArticleDOI
Ionic liquid solutions as extractive solvents for value-added compounds from biomass
TL;DR: An overview on the use of ILs and their mixtures with molecular solvents for the extraction of value-added compounds present in natural sources and critical analysis on the economic impact versus the extraction performance of IL-based methodologies is carried out.
Journal ArticleDOI
Molecularly imprinted solid phase extraction coupled to high-performance liquid chromatography for determination of trace dichlorvos residues in vegetables
TL;DR: In this paper, a highly selective imprinted polymer by a room temperature ionic liquid-mediated bulk polymerization technique, using dichlorvos as the template, methacrylic acid as the functional monomers, and trimethylolpropane trimethacrylate as the crosslinker, was characterized by FT-IR, static and kinetic adsorption experiments.
Journal ArticleDOI
Development of a highly sensitive and specific monoclonal antibody-based enzyme-linked immunosorbent assay (ELISA) for detection of Sudan I in food samples.
TL;DR: The mAb-based ELISA proven to be a feasible quantitative/screening method for Sudan I analysis in food samples with the properties of high sensitivity, specificity, simplicity of sample pretreatment, high sample throughput and low expense.
Journal ArticleDOI
Determination of Sudan I in paprika powder by molecularly imprinted polymers-thin layer chromatography-surface enhanced Raman spectroscopic biosensor.
TL;DR: A novel biosensor combining molecularly imprinted polymers, thin layer chromatography, TLC and surface enhanced Raman spectroscopy could determine Sudan I levels in paprika powder to 1 ppm (or 2 ng/spot) and can be applied as a rapid, low-cost and reliable tool for screening Sudan I adulteration in foods.
References
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Journal ArticleDOI
Molecular Imprinting in Cross‐Linked Materials with the Aid of Molecular Templates— A Way towards Artificial Antibodies
TL;DR: In this article, the authors present a method analogous to a mechanism of antibody formation proposed earlier, by which in the presence of interacting monomers a cross-linked polymer is formed around a molecule that acts as a template.
Journal ArticleDOI
Molecular imprinting for drug bioanalysis. A review on the application of imprinted polymers to solid-phase extraction and binding assay.
TL;DR: Molecular imprinted polymers have been applied as selective sorbents in several analytical techniques, including liquid chromatography, capillary electrophoresis and capillary electrochromatography, solid phase extraction, and immunoassay as mentioned in this paper.
Journal Article
Sudan I Is a Potential Carcinogen for Humans Evidence for Its Metabolic Activation and Detoxication by Human Recombinant Cytochrome P450 1A1 and Liver Microsomes
TL;DR: A carcinogenic potency of this rodent carcinogen for humans is strongly suggested by the first report on the metabolism of Sudan I by human CYP enzymes, which found that human microsomes were competent in activating Sudan I to form adducts with DNA.
Journal ArticleDOI
Advanced solid phase extraction using molecularly imprinted polymers for the determination of quercetin in red wine.
TL;DR: The first application combining MIPs with SPE for advanced beverage analysis is reported, demonstrating the potential of molecularly imprinted solid phase extraction for rapid, selective, and cost-effective sample pretreatment.
Journal ArticleDOI
Fast determination of Sudan I by HPLC/APCI-MS in hot chilli, spices, and oven-baked foods.
Fernando Tateo,Monica Bononi +1 more
TL;DR: A HPLC/APCI-MS method useful for identification and quantitation of Sudan I, also at very low levels in hot chilli, other spices, and oven-baked foods is proposed.