Journal ArticleDOI
Synthesis, characterization, reactivity and structure of some mono and binuclear (η6-p-cymene)ruthenium(II) complexes
Dharmendra Kumar Gupta,A. N. Sahay,Daya Shankar Pandey,N. K. Jha,Pankaj Sharma,G. Espinosa,Armando Cabrera,M. Carmen Puerta,Pedro Valerga +8 more
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TLDR
In this paper, the binuclear complex [Ru(η6-C10H14)Cl2(CNPy)] has been determined by X-ray crystallography and its structure is characterized by microanalyses and spectroscopic studies (IR, 1H-, 13C-, 31P-NMR).About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1998-10-15. It has received 46 citations till now.read more
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Developments in the coordination chemistry of stibine ligands
William Levason,Gillian Reid +1 more
TL;DR: In this paper, the development in the chemistry of stibine and bismuthine ligands in the period 1991-2005 are reviewed, including new ligand syntheses, ligand properties including bonding and steric effects, trans influence and trans effects.
Journal ArticleDOI
DNA binding and topoisomerase II inhibitory activity of water-soluble ruthenium(II) and rhodium(III) complexes.
TL;DR: Water-soluble piano-stool arene ruthenium complexes based on 1-(4-cyanophenyl)imidazole (CPI) and 4-Cyanopyridine (CNPy) with the formulas [(eta6-arene)RuCl2(L)] have been prepared and the molecular structure of analogous rhodium(III) complex has been determined crystallographically.
Journal ArticleDOI
Half-sandwich RuCl2(η6-p-cymene) core complexes containing sulfur donor aroylthiourea ligands: DNA and protein binding, DNA cleavage and cytotoxic studies
TL;DR: The spectroscopic evidence showed good binding efficacy of the complexes with BSA and the alterations in the secondary structure of BSA by the Ru(ii) complexes were confirmed by synchronous fluorescence spectra.
Journal ArticleDOI
Stable mononuclear and binuclear ruthenium(II) arene complexes with multiple N-donor poly-pyridyl ligands: synthesis, spectroscopic and structural characterization. Single crystal X-ray structure of [(η6-C10H14)RuCl(bppz)]BF4
TL;DR: In this paper, the authors showed that the reaction of 2,3-bis(2-pyridyl)-pyrazine (bppz) with dimeric chloro-bridged dimeric arene ruthenium complexes [{(η6-arene)RuCl2}2] (arene=p-cymene or hexamethyl benzene) gives highly stable cationic mono and binuclear complexes with the formulation [(η 6-C10H14)RuCL(b ppz)]+ and [
Journal ArticleDOI
Synthesis of Ru(II)–benzene complexes containing aroylthiourea ligands, and their binding with biomolecules and in vitro cytotoxicity through apoptosis
Kumaramangalam Jeyalakshmi,Jebiti Haribabu,Chandrasekar Balachandran,Nattamai Bhuvanesh,Nobuhiko Emi,Ramasamy Karvembu +5 more
TL;DR: The Ru(II) complexes have a significant ability to induce cell death by apoptosis and were screened for a panel of cancer cell lines like HepG2, A549, MCF7 and SKOV3.
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Journal ArticleDOI
Arene ruthenium(II) complexes formed by dehydrogenation of cyclohexadienes with ruthenium(III) trichloride
TL;DR: In this article, the same authors compared their results with available data on arene exchange in arenetricarbonylchromium complexes and discussed in terms of electronic and steric effects on metal-arene bonding.
Journal ArticleDOI
Synthesis and structural characterization of η6-arene-ruthenium(II) complexes of alanine and guanine derivatives
William S. Sheldrick,S. Heeb +1 more
TL;DR: The η 6 -arene-ruthenium(II) complexes of L-alanine (L-alaH) and Lalanine methyl ester (L -alaMe) have been prepared and their structures established by X-ray structural analysis.
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Structure and reactivity of ruthenium half-sandwich compounds: crystal and molecular structure and acetonitrile exchange kinetics and mechanism of tris(acetonitrile)(.eta.6-benzene)ruthenium(2+) and tris(acetonitrile)(.eta.5-cyclopentadienyl)ruthenium(+)
Werner Luginbuehl,Pascal Zbinden,Pierre Andre Pittet,Thomas Armbruster,Hans Beat Buergi,Andre E. Merbach,Andreas Ludi +6 more