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Journal ArticleDOI

Synthesis of alternating hydroxy- and methyl-substituted hydrocarbons by oxymercuration of cyclopropylcarbinols

David B. Collum, +2 more
- 01 Apr 1986 - 
- Vol. 108, Iss: 8, pp 2094-2096
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This article is published in Journal of the American Chemical Society.The article was published on 1986-04-01. It has received 273 citations till now. The article focuses on the topics: Aliphatic compound & Bicyclic molecule.

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N-Methylated cyclic RGD peptides as highly active and selective alpha(V)beta(3) integrin antagonists.

TL;DR: Cyclo(RGDf-N(Me)V-) (P5) was found to be even more active than L1 and is one of the most active and selective compounds in inhibiting vitronectin binding to the alpha(V)beta(3) integrin.
Journal ArticleDOI

Selective Carbon–Carbon Bond Cleavage for the Stereoselective Synthesis of Acyclic Systems

TL;DR: It is demonstrated that carbon-carbon bonds have the potential to be a general principle in organic synthesis for the regio-, diastereo-, and even enantioselective preparation of adducts despite the fact that C-C single bonds are among the least reactive functional groups.
Journal ArticleDOI

Semicorrin metal complexes as enantioselective catalysts. Part 2. Enantioselective cyclopropane formation from olefins with diazo compounds catalyzed by chiral (semicorrinato)copper complexes

TL;DR: Copper complexes of chiral, C2-symmetric semicorrin ligands were found to be efficient catalysts for the cyclopropane formation from olefins with diazo compounds as discussed by the authors.
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