Journal ArticleDOI
Synthesis of cycloalkenones via the intramolecular cyclopropanation of furanyl diazo ketones
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This article is published in Journal of Organic Chemistry.The article was published on 1986-12-01. It has received 26 citations till now. The article focuses on the topics: Rhodium(II) acetate & Diazo.read more
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Journal ArticleDOI
Application of Intramolecular Carbenoid Reactions in Organic Synthesis
Albert Padwa,Keith E. Krumpe +1 more
Book ChapterDOI
Donor-Acceptor-Substituted Cyclopropanes: Versatile Building Blocks in Organic Synthesis
TL;DR: In this article, the synthesis and ring opening reactions of vicinally donor-acceptor-substituted cyclopropanes are treated and a review of their properties is presented.
Journal ArticleDOI
Rhodium (II) catalyzed reactions of diazo-carbonyl compounds
Julian Adams,Denice M. Spero +1 more
Journal ArticleDOI
π-Nucleophile Traps for Metallonitrene/Alkyne Cascade Reactions: A Versatile Process for the Synthesis of α-Aminocyclopropanes and β-Aminostyrenes
TL;DR: The reaction of a sulfamate ester derived rhodium nitrenoid species with an alkyne produces a versatile intermediate, capable of cascading into a wide variety of secondary transformations.
Journal ArticleDOI
An Electrochemical Approach to the Guanacastepenes
TL;DR: An asymmetric approach toward the [6-7-5] ring system of the guanacastepenes is described.