Journal ArticleDOI
Synthesis of homo and block copolymers of norbornene with W(CO)6 via photo-initiation
B Gita,G. Sundararajan +1 more
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TLDR
In this paper, block copolymers of norbornene and phenylacetylene have been synthesized employing W(CO)6/CCl4 /hν system indicating formation of a metallacarbene as the active species.About:
This article is published in Tetrahedron Letters.The article was published on 1993-09-17. It has received 23 citations till now. The article focuses on the topics: Norbornene & Phenylacetylene.read more
Citations
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Journal ArticleDOI
Light-induced olefin metathesis
TL;DR: This survey of the relevant literature summarises past and present developments in the use of light to expedite olefin ring-closing, ring-opening polymerisation and cross-metathesis reactions.
Journal ArticleDOI
Ultrafast Infrared Mechanistic Studies of the Interaction of 1-Hexyne with Group 6 Hexacarbonyl Complexes
Jennifer E. Shanoski,Christine K. Payne,Matthias F. Kling,Elizabeth A. Glascoe,Charles B. Harris +4 more
TL;DR: In this article, the ultrafast solvation and rearrangement dynamics following the photolysis of M(CO)6 (M = Cr, Mo, W) in terminal alkyne solutions have been investigated.
Journal ArticleDOI
Photochemical reactions of Group 6 metal carbonyls with alkenes
TL;DR: In this article, a survey of Group 6 transition metal carbonyls with alkenes and the formation of alkene carbonyl complexes of the type: [M(CO)5(η2-alkene)], [M[M[CO]4[2]-2]-alkene] and [M [M]3[2] are discussed.
Journal ArticleDOI
Photoinduzierte Ringöffnungs-Metathese-Polymerisation (PROMP) mit photochemisch gebildeten Katalysatoren vom Schrock-Typ
Journal ArticleDOI
Synthesis of conjugated polymers with ferrocene units as pendants or as end-groups
TL;DR: In this paper, conjugated polymers with ferrocene units as pendants or as end-groups were synthesized using the classical metathesis polymerisation catalyst W(CO) 6 under photo-irradiation.
References
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Journal ArticleDOI
Photoassisted polymerization of terminal alkynes by W(CO)6 involving catalyst generation by an alkyne to vinylidene ligand rearrangement
Journal ArticleDOI
Reaction de metathese des olefines induite photochimiquement en presence d'un complexe de metal de transition : VI. Existence probable d'un metallodichlorocarbene primaire
TL;DR: In this paper, a mechanism for the formation of these compounds is outlined, and the mechanism for their formation is described in terms of the insertion of metalladichlorocarbene moieties into the carbon double bond.
Journal ArticleDOI
Metathesis of 2-pentene with the W(CO)6/CCl4/hv- system. Role and physical properties of the photogenerated precipitate
TL;DR: In this paper, the role and some characteristic properties of the precipitate formed upon irradiation of the W(CO) 6 /CCl 4 catalyst system in the photoinduced methathesis of 2-pentene were described.
Related Papers (5)
Hexacarbonyltungsten and carbon tetrachloride as a photochemical system for olefin metathesis
Agapios Agapiou,Edward McNelis +1 more