Journal ArticleDOI
Ring-Opening Metathesis Polymerization of Norbornene Using Vinylic Ethers as Chain-Transfer Agents: Highly Selective Synthesis of Monofunctional Macroinitiators for Atom Transfer Radical Polymerization
Reads0
Chats0
About:
This article is published in Macromolecules.The article was published on 2002-01-01. It has received 46 citations till now. The article focuses on the topics: Chain transfer & Radical polymerization.read more
Citations
More filters
Journal ArticleDOI
Metal vinylidenes and allenylidenes in catalysis: applications in anti-Markovnikov additions to terminal alkynes and alkene metathesis.
TL;DR: Since this initial report, various metal vinylidenes and allenylidenes, which are key activation intermediates, have proved extremely useful for many alkyne transformations and contributed to the rational design of new catalytic reactions.
Journal ArticleDOI
Telechelic polymers by living and controlled/living polymerization methods
TL;DR: In this paper, the authors describe the general techniques for the preparation of telechelic polymers by living and controlled/living polymerization methods, including atom transfer radical polymerization, nitroxide mediated radical polymerisation, reversible addition-fragmentation chain transfer polymerization and iniferters.
Journal ArticleDOI
Mechanistic transformations involving living and controlled/living polymerization methods
Yusuf Yagci,M. Atilla Tasdelen +1 more
TL;DR: In this paper, a review of transformation reactions involving living and controlled/living polymerization methods is presented, including step-growth, conventional and controlled free radical, cationic, anionic, group transfer, activated monomer Ziegler-Natta and metathesis reactions.
Journal ArticleDOI
Functional end groups for polymers prepared using ring-opening metathesis polymerization
TL;DR: An overview of the methods developed for different types and generations of metathesis catalysts that are typically used in polymerizations is presented and a 'field guide' of functionalization methods highlighting the factors to be considered when choosing the most appropriate approach is presented.
Journal ArticleDOI
Vinylideneruthenium complexes in catalysis
Hiroyuki Katayama,Fumiyuki Ozawa +1 more
TL;DR: Vinylideneruthenium complexes with the general formula [RuCl2(=C=CHR)L2] (L = PPr3i, PCy3, etc.) have been found to serve as good catalyst precursors with high efficiencies for ring-opening metathesis polymerization of cyclic olefins, ring opening/cross-metathesis between norbornene derivatives and vinyl chalcogenides, and (Z)-selective dimerization of terminal alkynes as mentioned in this paper.
References
More filters
Journal ArticleDOI
New challenges in biomaterials
Nicholas A. Peppas,Robert Langer +1 more
TL;DR: Approaches for controlling the interface between tissue and biomaterials and ways in which the engineered materials may contribute to medicine are considered.
Journal ArticleDOI
Living Polymerization Methods
TL;DR: Living polymerization techniques can be used to achieve a high degree of control over polymer chain architecture, which results in polymers with widely diverse physical properties, even though they are made from readily available low-cost monomers.
Journal ArticleDOI
Transition Metal Catalysis in Controlled Radical Polymerization: Atom Transfer Radical Polymerization
Journal ArticleDOI
Highly Efficient Ruthenium‐Based Catalytic Systems for the Controlled Free‐Radical Polymerization of Vinyl Monomers
TL;DR: A new set of ruthenium complexes such as 1 and 2 has been shown to mediate the controlled atom-transfer radical polymerization (ATRP) of vinyl monomers with exceptional efficiency.
Journal ArticleDOI
Design of initiators for living radical polymerization of methyl methacrylate mediated by ruthenium(ii) complex
TL;DR: A series of initiators have been developed for living radical polymerization of methyl methacrylate (MMA) mediated by ruthenium(II) complexes [e.g., RuCl2(PPh3)3; PhC6H5] as discussed by the authors.