Journal ArticleDOI
Photochemical reactions of Group 6 metal carbonyls with alkenes
TLDR
In this article, a survey of Group 6 transition metal carbonyls with alkenes and the formation of alkene carbonyl complexes of the type: [M(CO)5(η2-alkene)], [M[M[CO]4[2]-2]-alkene] and [M [M]3[2] are discussed.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2006-05-01. It has received 22 citations till now. The article focuses on the topics: Alkene & Ring-opening metathesis polymerisation.read more
Citations
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Journal ArticleDOI
Photochemically activated carbon monoxide release for biological targets. Toward developing air-stable photoCORMs labilized by visible light
TL;DR: An overview of recent efforts regarding several types of carbonyl complexes of the group 6 metal and of those in other laboratories that are focused on developing photochemical techniques for such CO delivery are provided.
Journal ArticleDOI
PdnCO (n = 1,2): accurate Ab initio bond energies, geometries, and dipole moments and the applicability of density functional theory for fuel cell modeling.
TL;DR: The use of relativistic effective core potentials for the treatment of PdCO and hence, by inference, for metal-CO interactions where the predominant bonding mechanism is charge transfer is justified.
Journal ArticleDOI
The chemistry of the carbon-transition metal double and triple bond : Annual survey covering the year 2006
TL;DR: A review of papers published in the year 2006 that focus on the synthesis, reactivity, or properties of compounds containing a carbon-transition metal double or triple bond is given in this article.
Journal ArticleDOI
Functionalization of carbon nanotubes with magnetic nanoparticles: general nonaqueous synthesis and magnetic properties
TL;DR: It is revealed that the hydrophobic interaction between nanoparticles and CNTs in hexane plays the critical role for the formation of CNT-based core-shell nanostructures.
Journal ArticleDOI
Theoretical analysis of frontier orbitals, electronic transitions, and global reactivity descriptors of M(CO)4L2 type metal carbonyl complexes: a DFT/TDDFT study
TL;DR: In this article, structural, electronic, and reactivity properties of characterized molybdenum and tungsten carbonyl complexes with benzimidazole and imidazoline derivative ligands were investigated using DFT-based calculation program ORCA.
References
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Book
Olefin metathesis and metathesis polymerization
Kenneth J. Ivin,I. C Mol +1 more
TL;DR: The metal carbene/metallacyclobutane mechanism has been studied extensively in the literature as mentioned in this paper, with a focus on the use of a ring-opening metathesis.
Journal ArticleDOI
Vibrational Spectra and Bonding in Metal Carbonyls. I. Infrared Spectra of Phosphine-substituted Group VI Carbonyls in the CO Stretching Region
C. S. Kraihanzel,F. A. Cotton +1 more
Journal ArticleDOI
Vibrational Spectra and Bonding in Metal Carbonyls. I. Infrared Spectra of Phosphine-substituted Group VI Carbonyls in the CO Stretching Region
F. A. Cotton,C. S. Kraihanzel +1 more