Journal ArticleDOI
Synthesis of imines from nitrobenzene and TiO2 particles suspended in alcohols via semiconductor photocatalysis type B
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In this paper, a nonaqueous suspension of titanium dioxide with nitrobenzene and different alcohols in deaerated conditions produces imines and aniline as main products.About:
This article is published in Tetrahedron Letters.The article was published on 2010-05-19. It has received 26 citations till now. The article focuses on the topics: Nitrobenzene & Aniline.read more
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Journal ArticleDOI
Selective Formation of Imines by Aerobic Photocatalytic Oxidation of Amines on TiO2
TL;DR: By using O-labeling experiments, the research group has discovered that an oxygen-atom transfer dominates the photocatalytic transformation of alcohols into the corresponding carbonyl compounds on TiO2 in benzotrifluoride.
Journal ArticleDOI
Heterogeneous photocatalytic organic synthesis: state-of-the-art and future perspectives
TL;DR: In this paper, a review is presented on achievements in heterogeneous photocatalytic organic synthesis, and a comparison is drawn between systems optimised for heterogeneous organic degradation and heterogeneous catalytic organics.
Journal ArticleDOI
Transforming CdS into an efficient visible light photocatalyst for selective oxidation of saturated primary C–H bonds under ambient conditions
TL;DR: In this paper, a cubic phase, sheet-structured semiconductor (CdS) sample is used as a visible-light-driven photocatalyst for the selective oxidation of saturated primary C-H bonds in alkyl aromatics with high activity and selectivity using molecular oxygen as a benign oxidant and benzotrifluoride as the solvent under ambient conditions, i.e., room temperature and atmospheric pressure.
Journal ArticleDOI
Visible‐Light‐Induced Selective Photocatalytic Aerobic Oxidation of Amines into Imines on TiO2
TL;DR: This report can be viewed as a prototypical system for the activation of C-H bonds adjacent to heteroatoms such as N, O, and S atoms, and oxofuctionalization with air or dioxygen as the terminal oxidant under visible-light irradiation using TiO(2) as the photocatalyst.
Journal ArticleDOI
Selective reductions using visible light photocatalysts of supported gold nanoparticles
TL;DR: In this article, the effects of the supports on photocatalytic synthesis using visible light were investigated and it was shown that the reaction power of the Au-H species depends on the energy of the excited electrons in Au-NPs.
References
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BookDOI
Electron transfer in chemistry
TL;DR: In this paper, principles, theories, methods and techniques are discussed for a wide range of applications, including redox catalysis/ molecular-level electronics/ other applications, as well as other applications.
Journal ArticleDOI
Photocatalysis: a promising route for 21st century organic chemistry
TL;DR: This account shows how photocatalysis is offering an alternative green route for the production of organics through selective photocatalytic conversions.
Journal ArticleDOI
Template-directed synthesis employing reversible imine bond formation
TL;DR: The imine bond--formed by the reversible condensation of an amine and an aldehyde--and its applications as a dynamic covalent bond in the template-directed synthesis of molecular compounds, will be the focus of this tutorial review.
Book
Photocatalysis Science and Technology
Masao Kaneko,Ichiro Okura +1 more
TL;DR: In this paper, photoelectrochemistry at Semiconductor/Liquid Interfaces is discussed, and a solution-phase processing of thin-filters is proposed for photoelectric TiO2 solar cells.
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John L. Ferry,William H. Glaze +1 more