Journal ArticleDOI
Synthesis of N-Benzyl Allylamnes by Reductive Amination with Selenophenol Generated Catalytically
Alain Guy,J. F. Barbetti +1 more
TLDR
In this article, a method for the preparation of N-Benzyl allylamines is described, where Selenophenol generated in catalytic quantities from diphenyldiselenide and sodium borohydride leads to reductive amination of allylamine by substituted benzaldehydes.About:
This article is published in Synthetic Communications.The article was published on 1992-03-01. It has received 6 citations till now. The article focuses on the topics: Reductive amination & Sodium borohydride.read more
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Journal ArticleDOI
Ruthenium-Catalyzed Allylic Substitution of Cyclic Allyl Carbonates with Nucleophiles. Stereoselectivity and Scope of the Reaction
TL;DR: In this article, the first investigation of the stereochemical course of the ruthenium-catalyzed allylic substitution reaction with nucleophiles was carried out, in which the reaction proceeds with an overall retention of configuration.
Journal ArticleDOI
The influence of benzylic protection and allylic substituents on the CuCl-TMEDA catalyzed rearrangement of N-allyl-N-benzyl-2,2-dihaloamides to γ-lactams. Application to the stereoselective synthesis of pilolactam
Franco Ghelfi,Franco Bellesia,Luca Forti,Gianluca Ghirardini,Romano Grandi,Emanuela Libertini,Maria C Montemaggi,Ugo Maria Pagnoni,Adriano Pinetti,Laurent De Buyck,Andrew F. Parsons +10 more
TL;DR: A number of N-benzylic protecting groups and allylic substituents have been investigated for the rearrangement, promoted by CuCl-TMEDA, of Nallyl-2,2-dihaloamides to 3,4-disubstituted γ-lactams.
Journal ArticleDOI
Nitrones in Organic Synthesis. Synthesis of Secondary Allyl Amines
TL;DR: In this article, the N-benzyl allyl amines have been reduced to the corresponding N-bromide amines by adding vinyl organomagnesium bromide to give the allyl hydroxylamines.
Reference EntryDOI
Advances in the Chemistry of Amino and Nitro Compounds
TL;DR: Amino compounds and nitro compounds with nucleophile reactions were studied in this paper, where the authors presented advances in chemistry of amino and Nitro compounds and showed that amino compounds can be synthesized with nucleophase reactions.
References
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Bull. Soc. Chim. Fr.
G. Hugel,G. Ourisson,J. Bye,J Miquel,D. P. Funeriu,Y He,H Bister,J-M Lehn,M Mousseron,J. M. Kamenka,Darvich +10 more
Journal ArticleDOI
Synthesis of Primary Allylic Amines
Journal ArticleDOI
Reduction of Schiff Bases. II. Benzhydrylamines and Structurally Related Compounds1a,b
John H. Billman,Kwang M. Tai +1 more
Journal ArticleDOI
Reduction of Schiff Bases with Sodium Borohydride
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